Chemistry of Heterocyclic Compounds

, Volume 31, Issue 1, pp 99–106 | Cite as

Synthesis and properties of derivatives ofsym-triazines 14. Cyanoethylation of 4,6-disubstituted 2-amino-sym-triazines

  • V. I. Kelarev
  • V. N. Kosbelev
  • R. A. Karakhanov
Article
  • 25 Downloads

Abstract

The cyanoethylation of 4,6-disubstituted 2-amino-sym-triazines containing alkyl trichloromethyl, and pyridyl groups was studied, and the corresponding dicyanoethyl derivatives were synthesized. It was shown that the yield of the latter and the duration of the reaction depend on the nature of the substituents in the ring of the initial amino-sym-triazines. A method of obtaining 2-(2-cyanoethyl)amino-sym-triazines is proposed based on the decyanoethylation and disproportionation of the dicyanoethyl derivatives as well as the trans-cyanoethylation.

Keywords

Organic Chemistry Pyridyl Disproportionation Trichloromethyl Pyridyl Group 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Copyright information

© Plenum Publishing Corporation 1995

Authors and Affiliations

  • V. I. Kelarev
  • V. N. Kosbelev
  • R. A. Karakhanov

There are no affiliations available

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