Organophosphorus derivatives of ethylenemine 2. Addition to dialkylphosphorousacid-ethyl eneamides of halogenated hydrocarbons and of halogens

  • N. P. Grechkin
Article
Received:
  • 22 Downloads

Summary

  1. 1.

    β-Chloroethylmethylarylamides of dialkylphosphoric acids were obtained by addition of halogenated hydrocarbons to ethyleneamides of dialkylphosphoric acids. The addition reaction is shown to proceed with rupture of the ring.

     
  2. 2.

    Addition of chlorine to ethyleneamides of dialkylphosphoric acids gave a series of β-chloroethylchloramides of dialkylphosphoric acids.

     
  3. 3.

    It is shown: a) that the synthesized chloramides undergo the Arbuzov rearrangement in the normal direction; b) the chloramides add on to ethyleneamides of dialkylphosphoric acids with formation of symmetrical bisdi-alkylphosphono-di-β-chloroethylhydrazines.

     

Keywords

Hydrocarbon Chlorine Halogen Normal Direction Addition Reaction 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
This is a preview of subscription content, log in to check access.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature Cited

  1. [1]
    N. P. Grechkin, Bull. Acad. Sci. USSR, Div. Chem. Sci. 1956, 538.Google Scholar
  2. [2]
    P. Lasselle and S. Sundet, J. Am. Chem. Soc. 63, 2374 (1941).Google Scholar
  3. [3]
    N. Kreutzkamp and H. Kayser, Naturwissenschaften 42, 14, 415 (1955).Google Scholar
  4. [4]
    B. A. Arbuzov, P. L. Alimov, and O. N. Fedorova, Bull. Acad. Sci. USSR, Div. Chem. Sci. 1956, 932.Google Scholar
  5. [5]
    G. Goldschmidt and R. Jahoda, Monatsh. 12, 83 (1891).Google Scholar

Copyright information

© Consultants Bureau 1957

Authors and Affiliations

  • N. P. Grechkin
    • 1
  1. 1.A. E. Arbuzov Institute of Chemistry of the Kazan Branch of the Academy of Sciences of the USSRUSSR

Personalised recommendations