Aquadifluoro(1,10-phenanthroline)copper(II) dihydrate: X-ray crystal structure reveals strong hydrogen bonds between ligand fluoride and lattice water molecules

  • John Emsley
  • Muhammad Arif
  • Paul A. Bates
  • Michael B. Hursthouse
Article

Abstract

C12H14CuF2N2O3,M=335.797, monoclinic, space groupP21/n,a=6.985(2),b=17.406(2),c=10.581(2) Å,β=92.41(2)°,V=1285(1) Å3,Dc=1.736 g cm−3,Z=4,F(000)=684,μ(Cu)=27.0 cm−1, λ=1.5418 Å,T=20°C, crystal dimensions=0.75×0.45×0.30 mm. The structure of the title compound shows it to be [Cu(phen)F2(H2O)]·2H2O with pentacoordinate-square pyramidal Cu(II), short Cu-F bonds [1.890(4) and 1.891(4) Å], and short F⋯H-O hydrogen bonds (ca. 2.68 Å) between the complex and lattice water molecule.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Babel, D. (1965)Z. Anorg. Allgem. Chem. 336, 200.Google Scholar
  2. Billy, C., and Haendler, H. M. (1957)J. Am. Chem. Soc. 79, 1049.Google Scholar
  3. Bukvetsky, B. V., Davidovich, R. L., and Simonov, V. I. (1975)Coord. Chem. 1, 1558.Google Scholar
  4. Bukvetsky, B. V., Muradyan, L. A., Davidovich, R. L., and Simonov, V. I. (1976)Sov. J. Coord. Chem. (Engl. Transl.)2, 869.Google Scholar
  5. Cromer, D. T., and Mann, J. B., (1968)Acta Crystallogr. A 24, 321.Google Scholar
  6. Cromer, D. T., and Liberman, D., (1970).J. Chem. Phys. 53, 1891.Google Scholar
  7. Edwards, A. J., and Peacock, R. D., (1959)J. Chem. Soc. 4126.Google Scholar
  8. Edwards, S. L., Poulos, T. L., and Kraut, J. (1984)J. Biol. Chem. 259, 12984.PubMedGoogle Scholar
  9. Emsley, J. (1980)Chem. Soc. Rev. 9, 91.Google Scholar
  10. Emsley, J., Reza, N. M., Dawes, H. M., and Hursthouse, M. B. (1986)J. Chem. Soc. Daltan Trans., 313.Google Scholar
  11. Emsley, J., Arif, M., Bates, P. A., and Hursthouse, M. B. (1987)J. Chem. Soc. Dalton Trans., in press.Google Scholar
  12. Fourquet, J. L., Plet, F., and De Pape, R. (1981)Rev. Chim. Miner. 18, 19.Google Scholar
  13. Friebel, C., Propach, V., and Reinen, D. (1976)Z. Naturforsch. Teil B 31, 1574.Google Scholar
  14. Green, M. L. H., Parkin, G., Mingqin, C., and Prout, K. (1984)J. Chem. Soc. Chem. Commun., 1400.Google Scholar
  15. Gibbs, P. R., Graves, P. R., Gulliver, D. J., and Levason, W. (1980)Inorg. Chim. Acta 45, L207.Google Scholar
  16. Haegele, R., and Babel, D. (1974)Z. Anorg. Allgem. Chem. 409, 11.Google Scholar
  17. Hursthouse, M. B., Jones, R. A., Malik, K. M. A., and Wilkinson, G. (1979)J. Am. Chem. Soc. 101, 4128.Google Scholar
  18. Jacobsen, R. A., and Jensen, W. P. (1981)Inorg. Chim. Acta 52, 205.Google Scholar
  19. Knox, K. (1959)J. Chem. Phys. 30, 991.Google Scholar
  20. Kutsky, R. J. (1981)Handbook of Vitamins, Minerals and Hormones 2nd edn., Van Nostrand Reinhold, New York.Google Scholar
  21. North, A. C. T., Phillips, D. C., and Mathews, F. S. (1968)Acta Crystallogr. 24, 351.Google Scholar
  22. Okazaki, A., and Suemune, Y. (1961)J. Phys. Soc. Jpn. 16, 176.Google Scholar
  23. Prince, E. (1972)J. Chem. Phys. 56, 4352.Google Scholar
  24. Rietmeijer, F. J., de Graaff, R. A. G., and Reedijk, J. (1984)Inorg. Chem. 23, 151.Google Scholar
  25. Sheldrick, G. M. (1976)Shelx 76, program for crystal structure determination (University of Cambridge).Google Scholar
  26. Sheldrick, G. M. (1986)Shelx 86, program for crystal structure solution (University of Gottingen).Google Scholar
  27. ten Hoedt, R. W. M., Reedijk, J., and Verschoor, C. G. (1981)Recl. Trav. Chim. Pays-Bas 100, 400.Google Scholar
  28. Velthuizen, W. C., Haasnoot, J. G., Kinneging, A. J., Rietmeijer, F. J., and Roedijk, J. (1983)J. Chem. Commun., 1366.Google Scholar

Copyright information

© Plenum Publishing Corporation 1987

Authors and Affiliations

  • John Emsley
    • 1
  • Muhammad Arif
    • 1
  • Paul A. Bates
    • 2
  • Michael B. Hursthouse
    • 2
  1. 1.Department of ChemistryKing's CollegeStrand, London
  2. 2.Department of ChemistryQueen Mary CollegeLondon

Personalised recommendations