Structure of (chloranilato)bis(tri-n-butylphosphine)palladium(II)

  • R. F. Johnston
  • D. G. VanDer Veer
  • R. A. Holwerda
Note
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Abstract

(Chloranilato)bis(tri-n-butylphosphine)palladium(II), [Pd(C6Cl2O4){P(C4H9)3}2] (chloranilic acid=2,5-dichloro-3,6-dihydroxy-p-benzoquinone): FW=718.02,P21/c,a=21.729(6),b=17.293(5),c=21.010(9) Å,β=112.62(3)°,V=7287.42 Å3,Z=8,Dc=1.309mg m−3, Mo, λ=0.710730 Å,μ=0.76 mm−1,F(000)=3008, finalR=0.087, 2594 observed reflections. Palladium is ligated by a distorted square planar P2O2 coordination sphere in the title compound. The two molecules per asymmetric unit differ in the arrangement of phosphine n-butyl chains, yielding two unique metal centers.

Keywords

Reflection Physical Chemistry Inorganic Chemistry Palladium Phosphine 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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References

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Copyright information

© Plenum Publishing Corporation 1992

Authors and Affiliations

  • R. F. Johnston
    • 1
  • D. G. VanDer Veer
    • 2
  • R. A. Holwerda
    • 3
  1. 1.Department of ChemistryMemphis State UniversityMemphis
  2. 2.Department of ChemistryGeorgia Institute of TechnologyAtlanta
  3. 3.Department of Chemistry and BiochemistryTexas Tech UniversityLubbock

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