Springer Nature is making SARS-CoV-2 and COVID-19 research free. View research | View latest news | Sign up for updates

Reactivity of the fluoride ion in polar aprotic solvents

  • 37 Accesses

  • 1 Citations

Conclusions

  1. 1.

    A kinetic study was carried out on the reaction of fluoride ion with O,S-diethyl methylphosphonate in polar, aprotic solvents which enhance the reactivity of the fluoride ion.

  2. 2.

    Regression equations were obtained which permit prediction of the reactivity of the fluoride ion in different solvents relative to the rate constants of reactions with anionic nucleophiles.

This is a preview of subscription content, log in to check access.

Literature cited

  1. 1.

    G. T. Davies, M. M. Demek, J. R. Sowa, and J. Epstein, J. Am. Chem. Soc.,93, 4093 (1971).

  2. 2.

    V. E. Bel'skii, G. S. Sakulin, and Yu. P. Prostov, Zh. Obshch, Khim.,51, 2442 (1981).

  3. 3.

    U. Mayer, V. Gutman, and W. Gerger, Monatschr. Chem.,106, 1235 (1975).

  4. 4.

    B. Kratochvil and H. L. Yerger, Fortschr. Chem. Forsch.,27, 1 (1972).

  5. 5.

    S. L. Maiofis, B. K. Filanovskii, and M. S. Grilikhes, Zh. Fiz. Khim.,53, 1257 (1979).

  6. 6.

    A. J. Parker, Chem. Rev.,69, 1 (1969).

  7. 7.

    J. J. Delpuech, Tetrahedron Lett., 2111 (1965).

  8. 8.

    P. Muller and B. Siegried, Helv. Chem. Acta,55, 2400 (1972).

  9. 9.

    D. L. Fowler and C. A. Kraus, J. Am. Chem. Soc.,62, 1140 (1940).

Download references

Author information

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 215–217, January, 1985.

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Bel'skii, V.E., Sakulin, G.S. Reactivity of the fluoride ion in polar aprotic solvents. Russ Chem Bull 34, 204–205 (1985). https://doi.org/10.1007/BF01157360

Download citation

Keywords

  • Fluoride
  • Kinetic Study
  • Aprotic Solvent
  • Methylphosphonate
  • Polar Aprotic Solvent