Catalytic properties of iron carbonyls supported on zeolites in hydrocarbon synthesis from CO and H2
Physical Chemistry
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Conclusions
- 1.
It has been shown that catalysts obtained on the basis of iron pentacarbonyl and NaY or CaY zeolite are active in the synthesis of alkanes from carbon monoxide and hydrogen.
- 2.
It has been shown by means of IR spectroscopy that when Fe(CO)5 is adsorbed on NaY or CaY zeolite, the complexes [Fe3(CO)11]2−, [Fe4(CO)13]2−, and [HFe3(CO)11]− are formed, and the active centers of the catalyst are formed from these complexes under the conditions of synthesis.
Keywords
Hydrogen Iron Spectroscopy Zeolite Hydrocarbon
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Literature cited
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© Plenum Publishing Corporation 1985