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Structural and spectroscopic properties of N-benzenesulphonylglycine complexes with copper (II)

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Abstract

In this paper are reported structural and spectroscopic properties of (N-benzenesulphonylglycinato) triaquacopper (II) (complex I) and dipotassium bis (N-benzenesulphonylglycinato) cuprate (II) (complex II). The crystals of (I) are monoclinic, space groupP21/c,Z=4, withα=12.736(4),b=10.292(3),c=10.402(3) Å,β=109.41(2)° while those of complex (II) are orthorhombic, space groupPbca, witha=23.333(8),b=10.508(4),c=16.989(5) Å. In both complexes the aminoacid molecules act as bidentatevia carboxylic oxygen and the amide nitrogen atom; in (I) three water molecules complete the coordination to tetragonal pyramidal, while in (II) coordination is square planar, tetrahedrally distorted involving two ligand molecules. The structure (I) was refined to a finalR index of 0.0596 and (II) toR=0.0466.

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References

  1. Antolini, L., Battaglia, L. P., Battistuzzi Gavioli, G., Bonamartini Corradi, A., Grandi, G., Marcotrigiano, G., Menabue, L., and Pellacani, G. C. (1983)J. Am. Chem. Soc. 105, 4333.

  2. Antolini, L., Battaglia, L. P., Battistuzzi Gavioli, G., Bonamartini Corradi, A., Grandi, G., Marcotrigiano, G., Menabue, L., and Pellacani, G. C. (1983)J. Am. Chem. Soc. 105, 4327.

  3. Antolini, L., Battaglia, L. P., Bonamartini Corradi, A., Marcotrigiano, G., Menabue, L., and Pellacani, G. C. (1985)J. Am. Chem. Soc. 107, 1369.

  4. Antolini, L., Menabue, L., Saladini, M., and Sola, M. (1988)Inorg. Chim. Acta 152, 17.

  5. Chaudhuri, S. (1984)J. Chem. Soc. Dalton Trans. 779.

  6. International Tables for X-Ray Crystallography (1974), vol. IV (Kynoch Press, Birmingham, England).

  7. Johnson, C. K. (1965)Ortep, Report ORNL-3794, (Oak-Ridge National Laboratory, Oak Ridge, Tenn.).

  8. Nardelli, M., (1983)Comput. Chem. 7, 95.

  9. Sheldrick, G. M. (1976)Shelx,System of computing programs (University of Cambridge).

  10. Ugozzoli, F. (1983)Assorb A program for Walker and Stuard's absorption correction, (University of Parma).

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Battaglia, L.P., Corradi, A.B., Pelosi, G. et al. Structural and spectroscopic properties of N-benzenesulphonylglycine complexes with copper (II). Journal of Crystallographic and Spectroscopic Research 21, 313–319 (1991). https://doi.org/10.1007/BF01156083

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Keywords

  • Oxygen
  • Nitrogen
  • Copper
  • Physical Chemistry
  • Inorganic Chemistry