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Mechanism of modifying skeletal copper catalyst for asymmetric hydrogenation

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Conclusions

  1. 1.

    Copper tartrate complexes that partially go into solution are formed on the surface of a copper catalyst when skeletal copper is modified with (2R,3R)-(+)-tartaric acid.

  2. 2.

    The character of the modifier-catalyst bond is close to the character of the modifier-metal bond in the corresponding complex.

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Literature cited

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 206–207, January, 1978.

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Vedenyapin, A.A., Klabunovskii, E.I., Leonova, E.V. et al. Mechanism of modifying skeletal copper catalyst for asymmetric hydrogenation. Russ Chem Bull 27, 180–181 (1978). https://doi.org/10.1007/BF01153237

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Keywords

  • Hydrogenation
  • Copper
  • Tartrate
  • Tartaric Acid
  • Copper Catalyst