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The regeneration of stable iminoxy radicals in the inhibited radiation-induced oxidation of hydrocarbons

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Conclusions

In the irradiation of hydrocarbon solutions of iminoxy radicals in the presence of oxygen, regeneration of the radicals from their radiolysis products is observed. A possible mechanism for the regeneration process was examined.

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Literature cited

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    M. F. Romantsev, N. V. Lysum, M. V. Sudnik, and G. F. Pavelko, Khim. Vys. Énerg.,6, 100 (1972).

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    T. Ya. Livertovskaya, M. F. Romantsev, M. V. Sudnik, I. M. Lukashenko, and E. S. Brodskii, Khim. Vys. Énerg.,7, 458 (1973).

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    A. B. Shapiro, M. V. Sudnik, M. F. Romantsev, and É. G. Rozantsev, Author's Certificate No. 435235 (Aug. 31, 1972); Byul, Izobr., No. 25 (1974).

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    B. V. Rozynov, M. V. Sudnik, A. B. Shapiro, V. L. Sadovskaya, I. A. Bogdanova, O. S. Reshetova, L. G. Nekhamkina, E. S. Brodskii, M. R. Romantsev, and E. G. Rozantsev, Izv. Akad. Nauk SSSR, Ser. Khim., 816 (1975).

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    R. Holroyd and W. Burns, Hydrocarbons. Aspects of Radiolysis [Russian translation], Izd. Mir (1971).

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    G. A. Lovtun, V. A. Golubev, and A. A. Aleksandrov, Izv. Akad. Nauk SSSR, Ser. Khim., 793 (1974).

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    N. A. Balk and G. M. Zimina, Khim. Vys. Énerg.,3, 92 (1969).

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2813–2816, December, 1975.

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Sudnik, M.V., Romantsev, M.F., Shapiro, A.B. et al. The regeneration of stable iminoxy radicals in the inhibited radiation-induced oxidation of hydrocarbons. Russ Chem Bull 24, 2702–2704 (1975). https://doi.org/10.1007/BF01152883

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Keywords

  • Oxidation
  • Oxygen
  • Hydrocarbon
  • Regeneration Process
  • Radiolysis Product