By the reaction of diethyl and dibutyl phosphorochloridates with glycine in an aqueous medium in presence of a tertiary amine N-(diethoxyphosphinyl)- and N-(dibutoxyphosphinyl)-glycines were prepared.
Some mono- and di-substituted amides of N-(dialkoxyphosphinyl)glycines were prepared in which the substituents were alkyl (CH3; C2H5; i-C3H7; i-C4H9; C4H9), hydroxy, 2,2,2-trichloro-1-hydroxyethyl, and hydroxymethyl groups.
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Alimov, P.I., Fedorova, O.N. N-phosphorylation of glycine and some of its derivatives. Russ Chem Bull 15, 1316–1318 (1966). https://doi.org/10.1007/BF01151362
- Aqueous Medium