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Decomposition of benzenediazonium fluoborate in benzenesulfonic esters and in acetophenone

  • L. G. Makarova
  • M. K. Matveeva
Article
  • 29 Downloads

Summary

  1. 1.

    Phenyl formed by the decomposition of benzenediazonium fluoborate in methyl and ethyl benzenesulfonates acts only on the alkoxysulfonyl group in these esters and in both cases gives phenyl benzenesulfonate.

     
  2. 2.

    In the decomposition of benzenediazonium fluoborate in acetophenone, 3′- and 4′-phenylacetophenones are formed in the ratio of 4∶1.

     
  3. 3.

    These reactions constitute proof of the heterolytic character of the decomposition of benzenediazonium fluoborate.

     

Keywords

Methyl Ester Ethyl Phenyl Acetophenone 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Consultants Bureau Inc. 1959

Authors and Affiliations

  • L. G. Makarova
    • 1
  • M. K. Matveeva
    • 1
  1. 1.Institute of Heteroorganic Compounds of the Academy of Sciences of the USSRUSSR

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