Synthesis and X-ray structural study of bis(2-sodiumsulfonylethyl) sulfoxide hexahydrate
Organic Chemistry
Received:
- 21 Downloads
Abstract
The structure of bis(2-sodiumsulfonylethyl) sulfoxide hexahydrate (1), which was synthesized by the reaction of divinyl sulfoxide with sodium metabisulfite in an aqueous ethanol medium, has been determined by X-ray structural analysis. Both Na+ cations are coordinated by six O atoms of crystallization water molecules and SO3 groups; the coordination sphere is a distorted octahedron. The crystals are stabilized by an extensive network of hydrogen bonds through the water molecules of crystallization.
Key words
divinyl sulfoxide sodium metabisulfite bis(2-sodiumsulfonylethyl) sulfoxide, X-ray structural studyPreview
Unable to display preview. Download preview PDF.
References
- 1.B. A. Trofimov and S. V. Amosova, inDivinilsul'foksid i ego proizvodnye [Divinyl Sulfoxide and Its Derivatives], Novosibirsk, Nauka, 1983 (in Russian).Google Scholar
- 2.B. A. Trofimov, A. N. Nikol'skaya, N. K. Gusarova, V. B. Kazimirovskaya, S. V. Amosova, N. A. Belogorlova, N. A. Chernysheva, M. N. Levina, T. V. Shelkova, D. V. Gendin, and M. G. Voronkov,Khim.-Farm. Th., 1987,1, 26 [Chem. Pharm. J., 1987,1 (Engl. Transl.)].Google Scholar
- 3.E. V. Bakhareva, N. N. Vasil'eva, V. B. Kazimirovskaya, Yu. A. Blednov, S. B. Seredenin, N. V. Myshkina, A. N. Nikol'skaya, S. V. Amosova, and M. G. Voronkov, inVsesoyuznaya konferentsiya po sintezu, farmakologii i klinicheskim aspektam novykh psikhotropnykh i serdechnososudistykh veshchestv, Tez. dokl. [All-Union Conf. on Synthesis, Pharmacology, and Clinical Aspects of New Psychotropic and Cardiovascular Substances, Abstrs. of Papers], Volgograd, 1989, 11 (in Russian).Google Scholar
- 4.S. V. Amosova, A. N. Nikol'skaya, N. V. Myshkina, N. A. Chernysheva, E. V. Shevchenko, V. B. Kazimirovskaya, E. V. Bakhareva, L. A. Mansurova, and M. N. Levina, inVsesoyuznyi seminar po khimii fiziologicheski aktivnykh soedinenii, Tez. dokl. [All-Union Workshop on Chemistry of Physiologically Active Compounds, Abstrs. of Papers], Chernogolovka, 1989, 16 (in Russian).Google Scholar
- 6.S. V. Amosova, V. S. Isaeva, P. M. Yashnova, A. N. Nikol'skaya, N. V. Myshkina, T. V. Ivanova, N. N. Rattel', A. K. Zhuravlev, and A. V. Rzhepka, USSR Pat. 1505929;Byul. Izobret., 1989,33, 111 (in Russian).Google Scholar
- 6.F. H. Allen, O. Kennard, D. G. Watson, L. Brammer, A. G. Orpen, and R. Taylor,J. Chem. Soc., Perkin Trans. 2, 1987, S1.Google Scholar
- 7.K.-T. Wei and D. L. Ward,Acta Crystallogr., 1977,B33, 522.Google Scholar
- 8.R. Tellgren, J. O. Thomas, and I. Olovsson,Acta Crystallogr., 1977,B33, 3500.Google Scholar
- 9.S. Menchetti and G. Sabelli,Acta Crystallogr., 1978,B34, 45.Google Scholar
- 10.L. P. Astakhova and V. I. Simonov.Kristallografiya, 1969,14, 3 [Sov. Phys. Crystallogr., 1969,14 (Engl. Transl.)].Google Scholar
- 11.S. Ghose and Che'Ng Wan,Acta Crystallogr., 1976,B32, 824.Google Scholar
- 12.Yu. V. Zefirov and P. M. Zorkii,Usp. Khim., 1989,58, 713 [Russ. Chem. Rev., 1989,58 (Engl. Transl.)].Google Scholar
- 13.R. G. Gerr, A. I. Yanovskii, and Yu. T. Struchkov,Kristallografiya, 1983,28, 1029 [Sov. Phys. Crystallogr., 1983,28 (Engl. Transl.)].Google Scholar
Copyright information
© Plenum Publishing Corporation 1995