The generation of radical pairs by low-temperature photolysis of solutions of sterically hindered quinones in aliphatic amines has been studied by ESR. The process of stabilization of radical pairs is related to molecular complexes between amines and quinones in solution.
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M. V. Serdobov,Izv. Akad. Nauk SSSR, Ser. Khim., 1984, 1416 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1984,33, 1304 (Engl. Transl.)].
M. V. Serdobov,Khim. Fiz., 1984,3, 841 [Sov. Chem. Phys., 1984,3 (Engl. Transl.)].
J. Kurita,J. Chem. Soc. Jpn., 1964,85, 833.
D. A. Weizsma and J. Kommandeur,J. Mol. Phys., 1967,13, 241.
V. M. Grigoryants, O. A. Anisimov, and Yu. N. Molin,Zh. Strukt. Khim., 1982,23, 4 [J. Struct Chem. (USSR), 1982,4 (Engl. Transl.)].
D. E. Wood and R. V. Lloyd,J. Chem. Phys., 1970,53, 3932.
Ions and Ion Pairs in Organic Reactions, Ed. M. Szwarc, Wiley, New York, 1972.
D. Griller, L. A. Howard, P. R. Marriott, and J. C. Scaino,J. Am. Chem. Soc., 1981,103, 619.
M. Goez and I. Sartorius,J. Am. Chem. Soc., 1993,115, 11123.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1736–1738, September, 1995.
This work was financially supported by the Russian Foundation for Basic Research (Project No. 95-03-09233a).
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Serdobov, M.V. Complexes of tertiary amines with hindered quinones. Russ Chem Bull 44, 1667–1669 (1995). https://doi.org/10.1007/BF01151288
- radical pairs, ESR spectrum
- amines, quinones, molecular complexes