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Synthese und Oxidation von14C-kernmarkierten Bikreosolen

Synthesis and oxygenation of14C-ring labelled bicreosoles. Specifically labelled phenol derivatives, IV

Spezifisch kernmarkierte Phenolderivate, 4. Mitt.

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Abstract

Bicreosol, labelled with14C in ring position 1.1′-, 4.4′-, 5.5′-, in the methyl- or in the methoxy substituent was oxygenated in 0.25m-NaOH. Isolation of low molecular fragments and determination of their specific activities indicate that at least two fragmentation pathways take place simultaneously: one with ring opening between the oxygen substituted carbon atoms, and one in which the bond between these atoms is not cleaved.

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Author information

Correspondence to Prof. Dr. Karl Kratzl.

Additional information

Meinem Lehrer, Herrn Prof. Dr. Dr. h.c. mult.H. Mark, zum 80. Geburtstag gewidmet.

3. Mitt.:K. Kratzl, P. Claus undf. W. Vierhapper, Mh. Chem.103, 100 (1972).

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Kratzl, K., Vierhapper, F.W. & Tengler, E. Synthese und Oxidation von14C-kernmarkierten Bikreosolen. Monatshefte für Chemie 106, 321–332 (1975). https://doi.org/10.1007/BF01150511

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