When dimethylaminoethyl methacrylate (DMAEM) is oxidized one inhibitor molecule repeatedly takes part in the acts of chain termination, which is due to the oxidation_reduction properties of the aminoperoxy radicals (RO2). The rate constants of the reactions of ten inhibitors of different classes with RO2 DMAEM at 50° were measured.
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Pliss, E.M., Aleksandrov, A.L. & Mogilevich, M.M. Multiple chain termination on inhibitor molecules during oxidation of dimethylaminoethyl methacrylate. Russ Chem Bull 26, 1327–1329 (1977). https://doi.org/10.1007/BF01143937
- Inhibitor Molecule
- Chain Termination