Construction of a scheme for the degradation of conjugated hydrocarbons
Physical Chemistry
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Conclusions
- 1.
The concept of degradation indices is introduced into the Huckel π-electron approximation treatment of conjugated systems, and the values of these indices used for comparative studies of various unsaturated molecule degradation schemes.
- 2.
Theoretical thermodynamic stability sequences obtained for certain hydrocarbons and heteroatomic molecules prove to be identical with the corresponding experimentally developed sequences. Mechanisms are proposed for polyacene and polyphenylene decompositions.
Keywords
Hydrocarbon Thermodynamic Stability Approximation Treatment Degradation Index Stability Sequence
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Literature cited
- 1.D. A. Bochvar, I. V. Stankevich, E. S. Krongauz, A. L. Rusanov, and V. V. Korshak, Vysokomol. Soed.,A9, 1429 (1967).Google Scholar
- 2.D. A. Bochvar, I. V. Stankevich, O. B. Tomilin, E. S. Krongauz, A. P. Travnikova, and V. V. Korshak, Dokl. Akad. Nauk SSSR,209, 1097 (1973).Google Scholar
- 3.D. H. Rouvray, Am. Sci.,61, 729 (1973).Google Scholar
- 4.O. B. Tomilin and I. V. Stankevich, Izv. Akad. Nauk SSSR, Ser. Khim., 1274 (1975).Google Scholar
- 5.M. Gelus, P.-M. Vay, and G. Berthier, Theor. Chim. Acta,9, 182 (1967).Google Scholar
- 6.H. Fisher and H. Kollmar, Theor. Chim. Acta,16, 163 (1970).Google Scholar
- 7.V. A. Khomutov, Dissertation, Moscow (1973).Google Scholar
- 8.V. V. Korshak, Chemical Structure and Thermal Characteristics of Polymers [in Russian], Nauka (1970).Google Scholar
- 9.M. M. Tessler, J. Polymer Preprints,6, 766 (1965).Google Scholar
- 10.M. M. Tessler, J. Polymer Sci.,A1, 2521 (1966).Google Scholar
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© Plenum Publishing Corporation 1977