Transition Metal Chemistry

, Volume 6, Issue 1, pp 42–44 | Cite as

Synthesis and characterization of cyclopentadienyl transition metal halides, part I, vanadium halides

  • Moisés Morán
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Summary

Reactions between η-Cp2V and PX3 (X=Cl, Br or I) yield the corresponding dihalogenated derivatives η-Cp2VX2 (X=Cl, Br or I). The oxidative addition of ICl and IBr to η-Cp2V gives mixed halogenated derivatives η-Cp2VIX (X=Cl or Br). All the compounds have been characterized by elemental analyses, magnetic moment measurements and i.r. and e.p.r. spectra.

Keywords

Physical Chemistry Inorganic Chemistry Catalysis Vanadium Halide 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Copyright information

© Verlag Chemie, GmbH 1981

Authors and Affiliations

  • Moisés Morán
    • 1
  1. 1.Departamento de Quimica Inorgánica Universidad Autónoma de MadridCantoblanco, MadridSpain

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