Springer Nature is making SARS-CoV-2 and COVID-19 research free. View research | View latest news | Sign up for updates

CIDNP study of the mechanism of the photodecomposition of 3-oxobutyltrimethyltin

  • 17 Accesses

Conclusions

  1. 1.

    The photodecomposition of 3-oxobutyltrimethyltin proceeds with breakage of the C-Sn bond and formation of radicals. Formation of a triplet radical pair of trimethylstannyl and 2-oxobutyl radicals occurs in decane and acetonitrile. A singlet radical pair of trichloromethyl and 2-oxobutyl radicals is formed in CCl4 Both these mechanisms occur in CHCl3.

  2. 2.

    3-Oxobutyltrimethyltin coordinates with the solvent in CCl4 and CDCl3.

This is a preview of subscription content, log in to check access.

Literature cited

  1. 1.

    H. G. Kuivila, J. E. Dixon, P. L. Maxfield, H. M. Scarpa, T. M. Torka, K.-H. Tsai, and K. R. Wursthorn, J. Organomet. Chem.,86, 89 (1975).

  2. 2.

    H. G. Kuivila, P. L. Maxfield, K.-H. Tsai, and J. E. Dixon, J. Am. Chem. Soc.,98, 104 (1976).

  3. 3.

    A. L. Buchachenko, V. Z. Sagdeev and K. M. Salikhov, Magnetic and Spin Effects in Chemical Reactions [in Russian], Nauka, Novosibirsk (1978), p. 96.

Download references

Author information

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1178–1180,May, 1985.

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Su, S.C., Podoplelov, A.V. & Sagdeev, R.Z. CIDNP study of the mechanism of the photodecomposition of 3-oxobutyltrimethyltin. Russ Chem Bull 34, 1078–1080 (1985). https://doi.org/10.1007/BF01142805

Download citation

Keywords

  • Acetonitrile
  • CDCl3
  • CHCl3
  • Photodecomposition
  • CCl4