Advertisement

Conversion of 4-hydroxy-3,5-di-tert-butylbenzonitrile to palladium and rhodium complexes

  • A. Z. Rubezhov
  • E. R. Milaeva
  • A. I. Prokof'ev
  • I. V. Karsanov
  • O. Yu. Okhlobystin
Organic Chemistry

Conclusions

Complexes of palladium (II) and rhodium (III) with 4-hydroxy-3,5-di-tert-butylbenzo-nitrile have been synthesized and it has been found that during their oxidation the metal-ligand bond is broken to yield the free nitrilophenoxyl radical in solution which under the action of the transition metal salt undergoes cyclotrimerization with formation of the non-symmetrical triazine.

Keywords

Oxidation Palladium Rhodium Triazine Metal Salt 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    E. R. Milaeva, L. Yu. Ukhin, V. B. Panov, A. Z. Rubezhov, A. I. Prokof'ev, and O. Yu. Okhlobystin, Dokl. Akad. Nauk SSSR,242, 125 (1978).Google Scholar
  2. 2.
    E. R. Milaeva, A. Z. Rubezhov, A. I. Prokoph'ev, and O. Yu. Okhlobystin, J. Organomet. Chem.,193, 135 (1980).Google Scholar
  3. 3.
    E. R. Milaeva, A. Z. Rubezhov, A. I. Prokoph'ev, A. G. Milaev, and O. Yu. Okhlobystin, J. Organomet. Chem.,188, C43 (1980).Google Scholar
  4. 4.
    E. Muller, K. Ley, K. Scheffler, and R. Mayer, Chem. Ber.,91, 2691 (1958).Google Scholar
  5. 5.
    L. Malatesta and C. Cariello, J. Chem. Soc., 2323 (1958).Google Scholar
  6. 6.
    E. Muller, K. Ley, K. Scheffler, R. Mayer, and A. Rieker, Chem. Ber.,92, 2278 (1959).Google Scholar
  7. 7.
    W. Z. Held, J. Organomet. Chem.,6, 292 (1966).Google Scholar
  8. 8.
    N. Yang and A. Castro, J. Am. Chem. Soc.,82, 6208 (1960).Google Scholar

Copyright information

© Plenum Publishing Corporation 1984

Authors and Affiliations

  • A. Z. Rubezhov
    • 1
  • E. R. Milaeva
    • 1
  • A. I. Prokof'ev
    • 1
  • I. V. Karsanov
    • 1
  • O. Yu. Okhlobystin
    • 1
  1. 1.A. N. Nesmeyanov Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

Personalised recommendations