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Investigation of the radiation stability of the carboxyl cation-exchange resin KB-6

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Conclusions

  1. 1.

    The ion-exchange resin KB-6 possesses differing radiation stability in the H+, Na+, and Cu+2 forms.

  2. 2.

    In the irradiation of the ion-exchange resin in the H+ and Cu+2 forms in water and in the Na+ form in the dry state in a dose of 0.2–1.8 · 1023 eV/g, the ion-exchange properties of the irradiated samples change negligibly; in the case of irradiation in the Na+ form in water at the same dose, a decrease in the capacity and an increase in the swelling are observed.

  3. 3.

    A hypothesis was advanced on the special role of the water of hydration in the transmission of absorbed energy in the ion-exchange resin.

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Literature cited

  1. 1.

    V. A. Nikashina, M. M. Senyavin, et al., Internat. J. Applied Radiation and Isotopes.4, 201 (1959).

  2. 2.

    I. A. Kuzin and A. M. Semushin, Zh. Prikl. Khimii,34, No. 3, 577 (1961).

  3. 3.

    K. M. Saldadze, A. B. Pashkov, and V. S. Titov, High-Molecular Ion-Exchange Compounds [in Russian], Moscow, p. 73 (1960).

  4. 4.

    P. Ya. Glazunov and G. B. Radzievskii, The Effects of Ionizing Radiations on Inorganic and Organic Systems [in Russian], Academy of Sciences USSR Press, p. 345 (1958).

  5. 5.

    S. Fisher and R. Kunin, J. Phys. Chem.8, 1030 (1956).

  6. 6.

    I. A. Kuzin and A. M. Semushin, Zh. Prikl. Khimii,34, No. 8, 1711 (1961).

  7. 7.

    E. D. Kiseleva, K. V. Chmutov, V. N. Krupnova, and N. D. Filatova, Transactions of the Second All-Union Conference on Radiation Chemistry [in Russian], Academy of Sciences USSR Press, p. 611 (1962).

  8. 8.

    V. E. Baroni, Vysokomolekul. Soedineniya,3, No. 2, 960 (1961).

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Setiya Khimicheskaya, No. 6, pp. 990–996, June, 1964

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Kiseleva, E.D., Chmutov, K.V., Klientovskaya, M.M. et al. Investigation of the radiation stability of the carboxyl cation-exchange resin KB-6. Russ Chem Bull 13, 925–929 (1964). https://doi.org/10.1007/BF01141643

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Keywords

  • Radiation
  • Hydration
  • Carboxyl
  • Special Role
  • Irradiate Sample