The IR absorption spectra of 24 semi- and thiosemicarbazones of certain aldehydes and ketones in the crystalline state in the region of 700–3700 cm−1 were obtained and interpreted.
It was concluded that the compounds studied exist in semi- and thiosemicarbazone structures in the solid state.
Several types of association of the investigated compounds by means of hydrogen bonds were proposed, mainly according to the type:
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Shagidullin, R.R., Sattarova, F.K., Raevskii, O.A. et al. Infrared absorption spectra of semi- and thiosemicarbazones of a number of aldehydes and ketones. Russ Chem Bull 13, 898–902 (1964). https://doi.org/10.1007/BF01141638
- Absorption Spectrum
- Solid State
- Crystalline State