Advertisement

Springer Nature is making SARS-CoV-2 and COVID-19 research free. View research | View latest news | Sign up for updates

Infrared absorption spectra of semi- and thiosemicarbazones of a number of aldehydes and ketones

  • 32 Accesses

Conclusions

  1. 1.

    The IR absorption spectra of 24 semi- and thiosemicarbazones of certain aldehydes and ketones in the crystalline state in the region of 700–3700 cm−1 were obtained and interpreted.

  2. 2.

    It was concluded that the compounds studied exist in semi- and thiosemicarbazone structures in the solid state.

  3. 3.

    Several types of association of the investigated compounds by means of hydrogen bonds were proposed, mainly according to the type:

This is a preview of subscription content, log in to check access.

Literature cited

  1. 1.

    Yu. P. Kitaev, G. K. Budnikov, and A. E. Arbuzov, Dokl. AN SSSR,127, 818 (1959).

  2. 2.

    S. G. Bogomolov, I. Ya. Postovskii, and Yu. N. Sheinker, Dokl. AN SSSR,91, No. 3 (1953).

  3. 3.

    W. H. T. Davison and (Miss)P. E. Christie, J. Chem. Soc.1955, 3389.

  4. 4.

    B. A. Gingras, R. W. Hornal, and C. H. Bayley, Canad. J. of Chem.38, No. 5, 712 (1960).

  5. 5.

    R. R. Shagidullin, F. K. Sattarova, Yu. P. Kitaev, and G. K. Budnikov, Izv. AN SSSR, Ser. Fiz., No. 10, 83 (1962).

  6. 6.

    L. J. Bellamy, “The Infra-red Spectra of Complex Molecules,” Methuen, London (1960).

  7. 7.

    W. West, The Use of Spectroscopy in Chemistry [Russian translation], Foreign Literature Press, Moscow (1959).

  8. 8.

    Richards and Thompson, J. Chem. Soc.,1947, 1248.

  9. 9.

    A. K. Chibisov and Yu. A. Pentin, Zh. Obshch. Khimii,31, No. 1, 11 (1961).

Download references

Author information

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Setiya Khimicheskaya, No. 6, pp. 960–965, June, 1964

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Shagidullin, R.R., Sattarova, F.K., Raevskii, O.A. et al. Infrared absorption spectra of semi- and thiosemicarbazones of a number of aldehydes and ketones. Russ Chem Bull 13, 898–902 (1964). https://doi.org/10.1007/BF01141638

Download citation

Keywords

  • Absorption Spectrum
  • Aldehyde
  • Solid State
  • Ketone
  • Crystalline State