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Cyclopentadienylethoxytitanium bis-8-hydroxyquinolate

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Summary

  1. 1.

    Cyclopentadienylethoxytitanium bis-8-hydroxyquinolate was prepared by the action of cyclopentadienyltriethoxytitanium on 8-quinolinol.

  2. 2.

    It was shown that, under the action of propyl alcohol, water, or oxygen under mild conditions the cyclopentadienyl ring is eliminated from cyclopentadienylethoxy titanium bis-8-hydroxyquinolate.

  3. 3.

    Chlorocyclopentadienyltitanium bis-8-hydroxyquinolate was prepared by the action of acetyl chloride on Cyclopentadienylethoxytitanium bis-8-hydroxyquinolate.

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Literature cited

  1. 1.

    J. S. Jennings, W. Wardlaw, and W. J. R. Way, J. Chem. Soc. 637 (1936).

  2. 2.

    A. N. Nesmeyanov, O. V. Nogina, A. M. Berlin, and Yu. P. Kudryavtsev, Izv. AN SSSR. Otd. khim. n. 1206 (1960).

  3. 3.

    H. Meister, Angew. Chem.69, 533 (1957).

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Nesmeyanov, A.N., Nogina, O.V. Cyclopentadienylethoxytitanium bis-8-hydroxyquinolate. Russ Chem Bull 12, 751–755 (1963). https://doi.org/10.1007/BF01134718

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Keywords

  • Oxygen
  • Alcohol
  • Chloride
  • Titanium
  • Acetyl