Dichloro complexes of PdII, [Pd(L−L′)Cl2], where L−L′=1-(thiomethyl)-2-(diphenylarsino)ethane (S−As) or 1-(thiomethyl)-2-(diphenylphosphino)ethane (S−P) andtrans-[PdL2Cl2], where L=diphenyl(2-phenylethyl)-phosphine (PE), diphenyl(1-naphthyl)phosphine (PN) orN-methyl-2-thiophenealdimine (SN), have been prepared and characterized. The reactions of these complexes with MeLi were investigated. The dimethyl complexes [Pd(L−L′)Me2] (L−L′=S−As, S−P) and [Pd(PE)Me2] were isolated and characterized. Reaction of [Pd(L−L′)Me2] (L−L′=S−As, S−P) with HCl affords the monomethyl derivatives [Pd(L−L′)Me(Cl)]. In contrast to the Pt analogues, [Pd(L−L′)Me2] and [Pd(L−L′)Me(Cl)] are relatively less stable than [Pt(L−L′)Me2] and [Pt(L−L′)Me(Cl)].
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Part I, A. M. Saleem and H. A. Hodali,Inorg. Chim. Acta,174, 223 (1990).
G. Calvin and G. E. Coates,J. Chem. Soc., 2008 (1960).
F. Ozawa, T. Ito, Y. Nakamura and A. Yamamoto,Bull. Chem. Soc. J.,54, 1868 (1981) and refs therein.
R. Tooze, K. W. Chiu and G. Wilkinson,Polyhedron,3, 1025 (1984).
R. D. Feltham and H. G. Metzger,J. Organomet. Chem.,33, 347 (1971).
G. K. Anderson and R. Kumar,Inorg. Chem.,23, 4064 (1984).
P. Rigo and M. Bressan,Inorg. Chem.,14, 1491 (1975).
H. A. Hodali,J. Chem. Eng. Data,32, 382 (1987).
D. F. Shriver,The Manipulation of Air-Sensitive Compounds, McGraw-Hill, New York, Ch. 5, 1969.
K. Issleib and K. Jasche,Chem. Ber.,100, 412 (1967).
K. Issleib and H. Volker,Chem. Ber.,94, 392 (1961).
M. P. Coakley, L. H. Young and R. A. Gallagher,J. Inorg. Nucl. Chem.,31, 1449 (1969).
J. R. Doyle, P. E. Slade and H. B. Jonassen,Inorg. Synth.,6, 216 (1960).
R. J. Cross,Chem. Soc. Rev.,14, 197 (1985).
F. Basolo and R. G. Pearson,Mechanisms of Inorganic Reactions, 2nd Edit., J Wiley, New York, 1967, p. 376.
T. Ito, H. Tsuchiya and A. Yamamoto,Bull. Chem. Soc. Jpn.,50, 1319 (1977).
E. O. Greaves, R. Bruce and P. M. Maitlis,J. Chem. Soc. Chem. Comm., 860 (1967).
R. J. Goodfellow, M. J. Hardy and B. F. Taylor,J. Chem. Soc. Dalton Trans., 2450 (1973).
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Saleem, A.M., Hodali, H.A. Synthesis and characterization of some methyl complexes of palladium(II). Part 2(1) . Transition Met Chem 16, 458–461 (1991). https://doi.org/10.1007/BF01129464
- Physical Chemistry
- Inorganic Chemistry