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Esters of cyclohexen-2-yl-1-phosphinic acid and some of their derivatives

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  1. 1.

    Esters of cyclohexen-2-yl-1-phosphinlc acid were synthesized by the action of sodium dialkylphosphite on 3-bromocyclohexene-1.

  2. 2.

    The corresponding oxides were obtained by oxidation with acetyl hydroperoxide.

  3. 3.

    The esters of 2,3-dihydroxycyclohexylphosphinic acid were obtained by hydration of the oxide.

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Literature cited

  1. 1.

    B. A. Arbuzov and E. N. Dianova, Izv. AN SSSR, Otd. khim. n. 1960,1399.

  2. 2.

    B. A. Arbuzov, V. S. Vinogradova, and N. A. Polezhaeva, Dokl. AN SSSR121, 641 (1958).

  3. 3.

    F. Fay and Lankelma, J. Amer. Chem. Soc.74, 4933 (1952).

  4. 4.

    D. R. Howton, J. Amer. Chem. Soc.69, 2060 (1947).

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Arbuzov, B.A., Dianova, E.N. Esters of cyclohexen-2-yl-1-phosphinic acid and some of their derivatives. Russ Chem Bull 10, 1197–1200 (1961). https://doi.org/10.1007/BF01118753

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  • Oxide
  • Sodium
  • Ester
  • Hydration
  • Acetyl