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Journal of Materials Science

, Volume 29, Issue 11, pp 2963–2967 | Cite as

Pest disintegration of thin MoSi2 films by oxidation at 500° C

  • T. C. Chou
  • T. G. Nieh
Article

Abstract

Thin molybdenum disilicide (MoSi2) films have been produced by magnetron sputter deposition, and subjected to oxidation tests for the study of “MoSi2 pest”-a phenomenon showing disintegration of a solid piece of MoSi2 into powdery products. The as-prepared films were of an amorphous structure. Oxidation of the films in air at 500° C led first to cracking of the films, and then the cracked pieces eventually evolved into disintegrated powders with a yellowish appearance. Secondary electron microscopy and Auger electron spectroscopy revealed that the reaction products consisted of MoO3 whiskers (platelets), Si-Mo-O fibres, SiO2 clusters, and some residual MoSi2. The disintegration of MoSi2 films appeared to be independent of their crystal structure; a similar phenomenon was also observed in crystallized films, with a metastable hexagonal structure, oxidized under the same conditions. The disintegration of the MoSi2 films is compared to and correlated with the “pest reaction” of bulk MoSi2.

Keywords

Auger MoO3 Auger Electron Spectroscopy Electron Spectroscopy Oxidation Test 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Chapman & Hall 1994

Authors and Affiliations

  • T. C. Chou
    • 1
  • T. G. Nieh
    • 2
  1. 1.Lockheed Research and Development DivisionPalo AltoUSA
  2. 2.Lawrence Livermore National LaboratoryLivermoreUSA

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