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IR spectra and structures of tellurite glasses

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Abstract

It is shown with IR spectral investigations that the short range order of certain tellurite glasses, obtained from monomineral crystalline phases, is similar to that of the crystals. They may contain the following polyhedra: TeO4-trigonal bipyramids (C2v symmetry), deformed TeO4 groups, TeO3 trigonal pyramids (C3v point symmetry), or combinations of these polyhedra. The introduction of V2O5 and MoO3 in the binary glasses leads to a TeO4 → TeO3 transition. MoO3 delays the decay of TeO4 groups in a wider concentration range.

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References

  1. 1.

    M. Arnaudov, V. Dimitrov andY. Dimitriev,Mater. Res. Bull. 17 (1982) 1121.

  2. 2.

    A. K. Yakhkind, in “Structure i fizikochimitsheskie svoistva neorganitsheskich stekol”, edited by A. G. Vlasov and V. A. Florinska (Chimia, Leningrad, 1974) p. 67.

  3. 3.

    N. Mochida, K. Takahashi, K. Nakata andS. Shibusawa,Yoguo-Kuokai-Shi. 86 (1978) 317.

  4. 4.

    Y. Dimitriev, M. Arnaudov andV. Dimitrov,Mh. Chem. 107 (1976) 1335.

  5. 5.

    Y. Dimitriev, V. Dimitrov andM. Arnaudov,J. Mater. Sci. 14 (1979) 723.

  6. 6.

    Y. Dimitriev, J. C. J. Bart, V. Dimitrov andM. Arnaudov,Z. Anorg. Allg. Chem. 479 (1981)

  7. 7.

    P. Tarte,Spectrochim. Acta 18 (1962) 467.

  8. 8.

    P. Tarte, in “Physics of Non-Crystalline Solids”, edited by J. A. Prins (North Holland, Amsterdam, 1964) p. 549.

  9. 9.

    H. Siebert, “Anwendungen der Schwingungsspektroskopie in der Anorganischen Chemie” (Springer. Berlin, 1966).

  10. 10.

    R. A. Condrat, in “Introduction to Glass Science”, edited by L. D. Pye, H. J. Stevens and W. C. Lacourse (Plenum Press, New York, London, 1972) p. 101.

  11. 11.

    O. Lindqvist,Acta Chem. Scand. 22 (1968) 977.

  12. 12.

    J. Galy, G. Meunier, S. Andersson andA. Aström,J. Solid State Chem. 13 (1975) 142.

  13. 13.

    R. J. Gillespie, “Molecular Geometry” (Van Nostrand Reinhold Company, London, 1972).

  14. 14.

    Y. Dimitriev, E. Gateff, E. Kashchieva andV. Dimitrov, Proceedings of the 11th International Congress on Glass, Prague 1, edited by J. Gotz (1977) p. 159.

  15. 15.

    V. Dimitrov, thesis, Sofia (1978).

  16. 16.

    Y. Dimitriev andV. Dimitrov,Mater. Res. Bull. 13 (1978) 1071.

  17. 17.

    Y. Dimitriev, V. Dimitrov andM. Arnaudov,Mh. Chem. 109 (1978) 791.

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Dimitriev, Y., Dimitrov, V. & Arnaudov, M. IR spectra and structures of tellurite glasses. J Mater Sci 18, 1353–1358 (1983). https://doi.org/10.1007/BF01111954

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Keywords

  • Pyramid
  • MoO3
  • V2O5
  • Short Range
  • Short Range Order