Formal kinetics of nonlinear photochemical reactions in solid solutions
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Abstract
Analytic expressions are derived for the rate constants of some two-quantum photochemical reactions. The limits of application of the approximations are discussed. It is shown that the quantum yield in two-photon sensitization (second photon absorbed by a molecule in a triplet state) is independent of the sensitizer when the substrate concentration is high. The concept of quantum yield for a nonlinear reaction is discussed.
Keywords
Solid Solution Quantum Yield Substrate Concentration Triplet State Photochemical Reaction
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