Transition Metal Chemistry

, Volume 14, Issue 6, pp 463–465 | Cite as

Polyazamacrocycles VI. Homo-trimetallic copper(II) and nickel(II) complexes with a new tri-cavity macrocycle

  • Ramesh Bembi
  • Tapashi G. Roy
  • Amrit K. Jhanji
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Summary

A new tri-cavity decaaza macrocycle (TCM) has been synthesised by the condensation of tetra(aminopropyl)-cyclam with diethanolamine. The new macrocyclic ligand forms tri-nuclear complexes, [Cu3(TCM)(H2O)2]-(ClO4)6 and [Ni3(TCM)(H2O)2](ClO4)6.

Keywords

Copper Physical Chemistry Nickel Inorganic Chemistry Catalysis 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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References

  1. (1a).
    See for example:D. E. Fenton and R. L. Lindvedt.J. Am. Chem. Soc.,100, 6367 (1978).Google Scholar
  2. (1b).
    R. R. Gagne and C. L. Spiro,J. Am. Chem. Soc.,102, 1443 (1980).Google Scholar
  3. (1c).
    R. W. Hay, R. Bembi and F. McLaren,Inorg. Chim. Acta,54, L161 (1981).Google Scholar
  4. (1d).
    B. C. Whitmore and R. Eisenberg,Inorg. Chem.,22, 1 (1983).Google Scholar
  5. (2).
    P. K. Coughlin and S. J. Lippard,Inorg. Chem.,23, 1446 (1984);J. Am. Chem. Soc.,106, 2328 (1984).Google Scholar
  6. (3).
    M. Vamashita, N. Ito and T. Ito,Inorg. Chem.,22, 2102 (1983).Google Scholar
  7. (4).
    R. W. Hay and M. P. Pujari,Inorg. Chim. Acta,99 75 (1985).Google Scholar
  8. (5).
    I. Murase, M. Mikuviya, H. Sonoda and S. Kida,J. Chem. Soc. Chem. Commun., 692 (1984).Google Scholar
  9. (6).
    R. W. Hay, R. Bembi and F. McLaren,Inorg. Chim. Acta,54, L161 (1981).Google Scholar
  10. (7).
    M. Ciampolini, M. Micheloni, N. Nardi, F. Vizza, A. Buttafava, L. Fabrizzi and A. Perotti,J. Chem. Soc. Chem. Commun., 998 (1984).Google Scholar
  11. (8).
    A. Poggi and B. Seghi,Inorg. Chem.,23, 3917 (1984).Google Scholar
  12. (9).
    A. Bencini, A. Bianchi, E. Garcia-Espana, M. Micheloni and P. Paoletti,Inorg. Chem.,27, 176 (1988).Google Scholar
  13. (10).
    B. Bosnich, C. K. Poon and M. L. Tobe,Inorg. Chem.,4, 1102 (1965).Google Scholar
  14. (11).
    K. P. Wainwright,J. Chem. Soc. Dalton Trans., 2117 (1980).Google Scholar
  15. (12).
    K. P. Wainwright,J. Chem. Soc. Dalton Trans., 1149 (1983).Google Scholar
  16. (13).
    R. Bembi, V. K. Bhardwaj, R. Singh, R. Singh, K. Taneja and S. Aftab,Inorg. Chem.,23, 4153 (1984).Google Scholar
  17. (14).
    E. K. Barefield, G. M. Freeman and D. G. Van Derveer,J. Chem. Soc. Chem. Commun., 1358 (1983).Google Scholar
  18. (15).
    R. Bembi, R. Singh, S. Aftab, T. G. Roy and A. K. Jhanjee,J. Coord. Chem.,14, 119 (1985).Google Scholar
  19. (16).
    J. W. L. Martin, J. H. Johnston and N. F. Curtis,J. Chem. Soc. Dalton Trans., 68 (1978).Google Scholar
  20. (17).
    P. Basu, S. Pal and A. Chakravorty,Inorg. Chem.,27, 1848 (1988).Google Scholar
  21. (18).
    M. Mikuriya, S. Kida and I. Murase,J. Chem. Soc. Dalton Trans., 1261 (1987).Google Scholar

Copyright information

© Chapman and Hall Ltd 1989

Authors and Affiliations

  • Ramesh Bembi
    • 1
  • Tapashi G. Roy
    • 1
  • Amrit K. Jhanji
    • 1
  1. 1.Department of ChemistryUniversity of RoorkeeRoorkeeIndia

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