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Reaction of keto alcohols with organophosphorus compounds

Communication 4. Synthesis of esters ofγ-ketophosphinic acids

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Conclusions

Trialkyl(aryl) phosphites and phosphonites react with 3-ketobutanol to give, respectively,γ-ketobutylphosphonic and phosphinic acids, while the phosphinites react to give the oxides of tertiary phosphines.

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimieheskaya, No. 5, pp. 1087–1092, May, 1970.

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Rizpolozhenskii, N.I., Mukhametov, F.S. Reaction of keto alcohols with organophosphorus compounds. Russ Chem Bull 19, 1027–1030 (1970). https://doi.org/10.1007/BF01084311

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Keywords

  • Oxide
  • Alcohol
  • Phosphine
  • Phosphite
  • Organophosphorus Compound