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Anisotropy of the polarizability and steric structure of adducts of maleic anhydride with acyclic dienes and their epoxy derivatives

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Conclusions

  1. 1.

    The dipole moments and Kerr constants of the adducts of diene synthesis of maleic anhydride with divinyl, 2,3-dimethylbutadiene, isoprene, piperylene, and their epoxy derivatives were determined.

  2. 2.

    Anhydrides of cyclohexenedicarboxylic acids are epoxidated in the cis-position; the conformations of the investigated compounds were determined.

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Literature cited

  1. 1.

    V. Klein, in: Advances in Stereochemistry [Russian translation], Goskhimizdat (1961), p. 151.

  2. 2.

    V. A. Naumov and V. M. Bezzubov, Zh. Strukt. Khim.,8, 530 (1967).

  3. 3.

    P. Ganis, C. Pedone, P. A. Temussi, and S. Watta, Atti. Accad. Naz Lincei Rend Cl. Sc. Fiz., Mat. e Natur.,35, 68 (1963).

  4. 4.

    V. A. Naumov and V. M. Bezzubov, Dokl. Akad. Nauk SSSR,171, 634 (1966).

  5. 5.

    A. N. Vereshchagin and S. G. Vul'fson, Zh. Strukt. Khim.,9, 1090 (1968).

  6. 6.

    B. A. Arbuzov, V. A. Naumov, and L. R. Shtrukov, Dokl. Akad. Nauk SSSR,163, 355 (1965).

  7. 7.

    B. A. Arbuzov, A. N. Vereshchagin, S. G. Vul'fson, and Z. G. Isaeva, Izv. Akad. Nauk SSSR, Ser. Khim., 1966 (1968).

  8. 8.

    W. Kumler, R. Boikess, P. Bruck, and S. Winstein, J. Amer. Chem. Soc.,86, 3126 (1964).

  9. 9.

    W. Doben and K. Pitzer, in: Steric Effects in Organic Chemistry [Russian translation], IL (1960), p. 40.

  10. 10.

    V. F. Kucherov, A. S. Onishchenko, and A. L. Shabanov, Izv. Akad. Nauk SSSR, Ser. Khim., 14 (1966).

  11. 11.

    S. Biagini and M. Cannas, Ricerca Scient, Part 2, Ser.A8, 1518 (1965).

  12. 12.

    A. S. Onishchenko, Diene Synthesis [in Russian], Izd-vo AN SSSR (1963), p. 44.

  13. 13.

    Tables of Interatomic Distances and Configurations, L. E. Sutton (editor), London (1958).

  14. 14.

    L. A. Gribov and E. M. Popov, Dokl. Akad. Nauk SSSR,145, 761 (1962).

  15. 15.

    K. Kitahonoki, H. Watanabe, and M. Sugiura, Chem. Ber.,95, 2354 (1962).

  16. 16.

    R. J. W. Le Fevre, B. J. Orr, and G. L. D. Ritchie, J. Chem. Soc.B, 273 (1966).

  17. 17.

    B. A. Arbuzov, L. A. Grozina, and A. N. Vereshchagin, Izv. Akad. Nauk SSSR, Ser. Khim., 548 (1969).

  18. 18.

    C. G. Le Fevre and R. J. W. Le Fevre, in: Physical Methods of Organic Chemistry, A. Weissberger (editor), Vol. 1, Part 3, Chap. 36, New York (1960).

  19. 19.

    A. N. Vereshchagin and L. A. Grozina, Teoret. i Éksperim. Khimiya,4, 361 (1968).

  20. 20.

    B. A. Arbuzov, L. A. Grozina, and I. N. Vereshchagin, Izv. Akad. Nauk SSSR, Ser. Khim., 2377 (1969).

  21. 21.

    B. Ottar, Acta Chem. Scand.,1, 283 (1947).

  22. 22.

    B. A. Arbuzov, L. A. Grozina, and A. N. Vereshchagin, Teoret. i Éksperim. Khimiya,4, 367 (1968).

  23. 23.

    M. S. Kletzel, Organic Reactions [Russian translation], Chap. 4, IL (1951), p. 7.

  24. 24.

    W. J. Bailey, J. Rosenberg, and L. J. Young, J. Amer. Chem. Soc.,76, 2251 (1954).

  25. 25.

    E. H. Farmer and F. L. Warren, J. Chem. Soc., 897 (1929).

  26. 26.

    D. Craig, J. Amer. Chem. Soc.,65, 1006 (1943).

  27. 27.

    V. F. Kucherov, V. M. Andreev, and I. N. Nazarov, Izv. AN SSSR, Otd. Khim. Nauk, 1262 (1959).

  28. 28.

    B. A. Arbuzov, Z. G. Isaeva, and E. G. Kataev, Uch.Zap.Kazansk.Gos. Un-ta,110, No. 9, 175 (1950).

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 995–1002, May, 1970.

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Vereshchagin, A.N., Anastas'eva, A.P. & Arbuzov, B.A. Anisotropy of the polarizability and steric structure of adducts of maleic anhydride with acyclic dienes and their epoxy derivatives. Russ Chem Bull 19, 943–948 (1970). https://doi.org/10.1007/BF01084293

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Keywords

  • Anisotropy
  • Epoxy
  • Adduct
  • Dipole Moment
  • Anhydride