Excess and excess partial molar volumes of mixing of the systems trimethylphosphate (TMP) and triethylphosphate (TEP) with water were determined at 15, 20, 25, 30 and 35°C. Negative deviation from ideal behavior were observed for the two systems studied, with a minimum at x TMP =0.40 and x TEP =0.35. Excess volume values in general decrease with temperature, and are smaller for the TMP-water system.
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Čomor, J.J., Kopečni, M.M. Excess and partial excess molar volumes of mixing trimethyl- and triethylphosphate with water. J Solution Chem 20, 945–953 (1991). https://doi.org/10.1007/BF01074954
- excess volume of mixing