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New rhodium(II)-rhodium(III) dinuclear complexes with 2-aminopyridine bridges

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Summary

The syntheses of the complexes [Rh2(ap)4X] (ap = the heterocyclic anion of 2-aminopyridine; X = Cl or Br) are described. The complexes have been characterized on the basis of elemental analysis, i.r., e.s.r. and electronic absorption spectra, and magnetic susceptibility measurements. The 2-aminopyridine anion behaves as bridging ligand, coordinatingvia the pyridine and amine nitrogen atoms in a way analogous to that in the dinuclear rhodium(II) carboxylates.

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Zuber, M. New rhodium(II)-rhodium(III) dinuclear complexes with 2-aminopyridine bridges. Transition Met Chem 11, 5–8 (1986). https://doi.org/10.1007/BF01064491

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Keywords

  • Nitrogen
  • Physical Chemistry
  • Inorganic Chemistry
  • Catalysis
  • Absorption Spectrum