Transition Metal Chemistry

, Volume 11, Issue 5, pp 170–171 | Cite as

Electrochemical studies of azido(imidazole) cobaloxime complexes

  • Jayanta K. Das
  • Vivekananda Chakravortty
  • Kailash C. Dash
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Summary

Cyclic voltammetric studies of a series of azido(imidazole) cobaloxime complexes in acetonitrile with tetraethylammonium perchlorate as the supporting electrolyte reveal the presence of the central cobalt atom in these complexes in the +III state. In addition to reductions to cobalt(II), cobalt(I) and cobalt(0) species, evidence for oxidation to cobalt(IV) also was noted.

Keywords

Oxidation Physical Chemistry Cobalt Inorganic Chemistry Acetonitrile 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Copyright information

© VCH Verlagsgesellschaft mbH 1986

Authors and Affiliations

  • Jayanta K. Das
    • 1
  • Vivekananda Chakravortty
    • 1
  • Kailash C. Dash
    • 1
  1. 1.Department of ChemistryUtkal UniversityVani Vihar, BhubaneswarIndia

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