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Pesticide and industrial chemical residues at the mouth of the grand, Saugeen and Thames rivers, Ontario, Canada, 1981–85

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Abstract

Water samples collected at the river mouth of the Grand, Saugeen and Thames rivers between January 1981 and December 1985 were analyzed for 20 herbicides, 25 insecticides and 3 fungicides that had been used in the basins. Thirteen herbicides were identified in river water; these ranged from single events in one basin over the five years to those appearing in most water samples from all three basins. Atrazine was the most frequently found pesticide present at measurable levels in 375 of 440 samples (85%). The second most frequently found pesticide was 2,4-D which was identified in 78 of 447 water samples (17%). No fungicides were detected in river water and only single events of two organophosphorus insecticides occurred in 446 samples analyzed (diazinon and malathion). Organochlorine insecticides were identified from both present and past use patterns. Heptachlor expoxide appeared as a breakdown product from the use of chlordane. The order by pesticide group in decreasing loadings at the river mouth were triazine herbicides < chloroacetanilide herbicides < chlorophenoxy and chlorobenzoic acid herbicides < organochlorine insecticides. The highest loadings at the river mouth were for atrazine, which ranged from 0.1 to 8.2 metric tonnes per basin representing between 0.2 and 2.1% of that applied in the basin. Loadings of alachlor, metolachlor, and cyanazine represented up to 0.5 metric tonnes at the Thames river mouth, but negligible amounts for the other basins. Loading of chlorophenoxy herbicides and insecticides were infinitely lower than the triazines and chloroacetanilide herbicides. Some organochlorines of industrial origin were sought however, other than in 1981 when polychlorobiphenyls (PCBs) were present at measurable level; none were detected between 1982 and 1985.

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References

  1. Anonymous (1979) Ontario Ministry of Agriculture and Food, 1979 Field Crop Recommendations, Publication 296, Parliament Buildings, Queen's Park, Toronto, Ontario, Canada

  2. -(1977) International Reference Group on Great Lakes Pollution from Land Use Activities. Quality Control Handbook for Pilot Watershed Studies, Internat Joint Commission, Windsor, Ontario, Canada

  3. -(1978) Environmental management strategy for the Great Lakes system. Pollution from Land Use Activities Reference Group (PLUARG). Final Report International Joint Commission, Windsor, Ontario, Canada

  4. -(1981–1985) Environment Canada, Water Survey of Canada, Inland Waters and Lands Directorate, Water Resources Branch, Water Survey of Canada, Ottawa, Canada

  5. Beste LE (ed) (1983) Herbicide Handbook, Fifth edition, Weed Sci Society of Am, Champaign, Illinois

  6. Bodo B, Unny TE (1983) Sampling strategies for mass discharge estimation. J Environ Eng Vol 109, No 4, ASCE, Paper No 18139

  7. Coburn JA, Ripley BD, Chau ASY (1976) Analysis of pesticide residues by chemical derivatization. II. N-Methyl-carba-mates in natural water and soils. J Assoc Offic Anal Chem 59:188–196

  8. Coote DR, MacDonald EM, Dickinson WT, Ostry RL, Frank R (1982) Agriculture and water quality in the Canadian Great Lakes Basin: I. Representative agricultural watersheds. J Environ Qual 11:473–481

  9. Frank R (1981) Pesticides and PCB in the Grand and Saugeen River basins. J Great Lakes Res 7(4):440–454

  10. Frank R, Braun HE, Sirons GJ, Holdrinet MVH, Ripley BD, Onn D, Coote R (1978) Stream flow quality-pesticides in eleven agricultural watersheds in Southern Ontario, Canada 1974–1977. PLUARG Tech Rep Int Joint Commission, Windsor, Ontario, Canada

  11. Frank R, Braun HE, Holdrinet MVH, Sirons GJ, Ripley BD (1982) Agriculture and water quality in the Canadian Great Lakes Basin: V. Pesticide use in 11 agricultural watersheds and presence in stream water, 1975–1977. J Environ Quality 11:497–505

  12. Holdrinet M (1974) Determination and confirmation of hexachlorobenzene in fatty samples in the presence of other residual halogenated hydrocarbon pesticides and polychlorinated biphenyls. J Assoc Offic Anal Chem 57:580–584

  13. Holdrinet MVH, Frank R, Thomas RL, Hetling LH (1978) Mirex in the sediments of Lake Ontario. J Great Lakes Res 4:69–74

  14. Magee W (1984) Survey of pesticide use in Ontario 1983. Economics Information Report 84-05, ISBN 0-7743-99459-7 Ont Ministry of Agriculture and Food, Legislative Buildings, Queen's Park, Toronto, Ontario, Canada M7A 1B6

  15. Mills PA, Bong BA, Kamps LR, Burke JA (1972) Elution solvent for Florisil® cleanup in organochlorine pesticide residue analysis. J Assoc Offic Anal Chem 55:39–43

  16. Ramsteiner K, Hormann WD, Eberle DO (1974) Multi-residue method for the determination of triazine herbicides in fieldgrown agricultural crops, water and soil. J Assoc Offic Anal Chem 57:192–201

  17. Ripley BD (1985) Gas Chromatography — mass spectrometry of acylalanine fungicides. J Agric Food Chem 33:560–563

  18. Scott WS (1979) Use of oil solvent materials for small herbicide spills. Bull Environ Contam Toxicol 23:123–128

  19. Sirons GJ, Frank R, Sawyer T (1973) Residues of atrazine, cyanazine and their phytotoxic metabolites in a clay loam soil. J Agric Food Chem 21:1016–1020

  20. Statistics Canada (1981) Census of Agriculture, Ontario, Catalogue No. 96-907, Ottawa, Canada

  21. Webber LR, Hoffman DW (1967) Origin, classification and use of Ontario soils. Publication 51, Ont Ministry of Agriculture & Food, Canada, p 58

  22. Worthing CR, Walker SB (1983) The Pesticide Manual, 7th Ed. Brit Crop Prot Council, Croyden, UK

  23. Yip G (1971) Improved method for determination of chlorophenoxy acid residues in total diet samples. J Assoc Offic Anal Chem 54:966–969

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Frank, R., Logan, L. Pesticide and industrial chemical residues at the mouth of the grand, Saugeen and Thames rivers, Ontario, Canada, 1981–85. Arch. Environ. Contam. Toxicol. 17, 741–754 (1988). https://doi.org/10.1007/BF01061980

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Keywords

  • PCBs
  • Atrazine
  • River Mouth
  • Triazine
  • Malathion