Journal of Statistical Physics

, Volume 52, Issue 5–6, pp 1307–1313 | Cite as

Liquid crystalline states of surfactant solutions of isotropie micelles

  • Carey Bagdassarian
  • William M. Gelbart
  • Avinoam Ben-Shaul
Articles

Abstract

We consider micellar solutions whose surfactant molecules prefer strongly to form small, globular aggregates in the absence of intermicellar interactions. At sufficiently high volume fraction of surfactant, the isotropic phase of essentially spherical micelles is shown to be unstable with respect to an orientationally ordered (nematic) state of rodlike aggregates. This behavior is relevant to the phase diagrams reported for important classes of aqueous amphiphilic solutions.

Key words

Micelle excluded volume liquid crystallinity self-assembly isotropic-nematic transition packing entropy 

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Copyright information

© Plenum Publishing Corporation 1988

Authors and Affiliations

  • Carey Bagdassarian
    • 1
  • William M. Gelbart
    • 1
  • Avinoam Ben-Shaul
    • 2
  1. 1.Department of ChemistryUniversity of CaliforniaLos Angeles
  2. 2.Department of Physical Chemistry, and Fritz Haber Molecular Dynamics Research CenterHebrew UniversityJerusalemIsrael

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