Far infrared transmission spectra of ferroelectric guanidine aluminium sulfate hexahydrate
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Abstract
Far IR transmission spectra of ferroelectric GASH are obtained at 300 K-80 K and 4 K for crystal plates cut perpendicular to C3 with increasing thicknesses.
Beer's law is well observed from t=20 μm to t=55 μm, which shows that such samples are homogeneous. For t=700 μm the computed absorption is higher than observed, and a surface layer model is proposed where the bulk is more transparent than the surface.
Similar effects have been observed in TGS where even for t=8 mm thick samples, the transmission of the lowest frequency band does not go to zero. A similar experiment is planned for GASH before making any definite conclusion on the evidence of surface layers in GASH.
Keywords
Aluminium Sulfate Surface Layer Frequency Band Transmission Spectrum
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References
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© Plenum Publishing Corporation 1987