Journal of Applied Electrochemistry

, Volume 20, Issue 4, pp 537–548

Particle size and structural effects in platinum electrocatalysis

  • S. Mukerjee
Reviews of Applied Electrochemistry 23

Abstract

Of the several factors which influence electrocatalytic activity, particle size and structural effects are of crucial importance, but their effects and mechanism of interaction,vis-a-vis overall performance, have been, at best, vaguely understood. The situation is further aggravated by the use of a wide range of experimental conditions resulting in non-comparable data. This paper attempts systematically to present the developments to date in the understanding of these structural interactions and to point out areas for future investigation. The entire content of this review has been examined from the context of the highly dispersed Pt electrocatalyst, primarily because it has been examined in the greatest detail. In the first two sections a general idea on the correlations between surface microstructure and geometric model is presented. Subsequently, indicators of a direct correlation between particle size and catalyst support synergism are considered. The structural and particle size effect on electrocatalysis is examined from the point of view of anodic hydrogen oxidation and cathodic oxygen reduction reactions. The hydrogen and oxygen chemisorption effects, presented with the discussion on the anodic and cathodic electrocatalytic reactions, provide important clues toward resolving some of the controversial findings, especially on the dependence of particle size on the anodic hydrogen oxidation reaction. Finally, the effect of alloy formation on the cathodic oxygen reduction reaction is discussed, providing insights into the structural aspect.

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References

  1. [1]
    R. V. Hardeveld and A. V. Montfoort,Surf. Sci. 4 (1969) 396.Google Scholar
  2. [2]
    K. Kinoshita, ‘Modern Aspects of Electrochemistry’, vol. 14. Plenum, New York (1983).Google Scholar
  3. [3]
    K. Kinoshita and P. Stonehart vol. 12 (1977) p. 183.Google Scholar
  4. [4]
    H. Knozinger,Adv. Catal. 25 (1976) 185.Google Scholar
  5. [5]
    T. C. Gonzalez, K. Aska, S. Namba and J. Turkevich,J. Phys. Chem. 66 (1962) 48.Google Scholar
  6. [6]
    H. L. Gruber,J. Phys. Chem. 66 (1962) 48.Google Scholar
  7. [7]
    O. M. Poltorak and V. S. Boronin,Russ. J. Phys. Chem. (Eng. transl.)49 (1965),40 (1966) 1436.Google Scholar
  8. [8]
    R. Hardeveld and F. Hartog,Proc. Int. Congr. Catal.; 4th, paper no. 70 (1968).Google Scholar
  9. [9]
    P. N. Ross Jr.,J. Electrochem. Soc. 126 (1979) 67.Google Scholar
  10. [10]
    V. M. Jalan and C. L. Bushnell, U.S. Patent 4,136,056 and 4,137,373 (23 Jan. 1979).Google Scholar
  11. [11]
    V. M. Jalan, ‘Preparation of highly dispersed platinum and its stabilization by carbon’.Meeting of Electrochem. Society, Montreal, Canada (9–14 May 1982).Google Scholar
  12. [12]
    A. Pebler,J. Electrochem Soc. 133 (1) (1986) 9.Google Scholar
  13. [13]
    V. M. Jalan, Microstructure of highly dispersed Pt catalyst and its interaction with carbon supports,Workshop on Oxygen Electrochemistry', Quail Hollow, Painesville, Ohio (2–4 May 1979).Google Scholar
  14. [14]
    L. J. Hillenbrand and J. W. Lacksonen,J. Electrochem. Soc. 122 (1965) 249.Google Scholar
  15. [15]
    J. Escard, C. Leclerc and J. P. Contour,J. Catal. 19 (1973) 31.Google Scholar
  16. [16]
    V. S. Bogotski and A. M. Snudkin,Electrochemica Acta 29 (5) (1984) 757–67.Google Scholar
  17. [17]
    A. V. Kobelev, R. M. Kobeleva and V. F. Ukhov,Dokl. Akad. Nank. (USSR)243 (1978) 692.Google Scholar
  18. [18]
    M. W. Brieter, “Electrochemical Processes in Fuel Cells. Springer-Verlag, Berlin and New York (1969).Google Scholar
  19. [19]
    R. Woods Jr.,Electroanal. Chem. 49 (1974) 217.Google Scholar
  20. [20]
    P. N. Ross Jr. in “Electrocatalysis of Fuel Cell Reactions”, Brookhaven Natl. Lab. Upton, New York (1978) p. 169.Google Scholar
  21. [21]
    M. Bold and M. Brieter,J. Electrochem. 64 (1970) 897.Google Scholar
  22. [22]
    L. Vertzh, I. A. Mosevich and I. Tverdovsky,Dokl. Akad. Nank. (SSSR)140 (1961) 149.Google Scholar
  23. [23]
    P. N. Ross Jr.,Electroanal. Chem. 76 (1977) 139.Google Scholar
  24. [24]
    F. G. Will,J. Electrochem. Soc. 112 (1965) 451.Google Scholar
  25. [25]
    G. C. Bond,Catalysis by Metals, Academic Press, New York (1962) pp. 162–170.Google Scholar
  26. [26]
    K. Kinoshita, J. Lundquist and P. Stonehart,J. Catal. 31 (1973) 325.Google Scholar
  27. [27]
    K. Kinoshita and P. Stonehart,Electrochem Acta 23 (1978) 45.Google Scholar
  28. [28]
    H. Angerstein-Kozlowska, W. B. A. Sharp and B. E. Conway, inProceedings of the Symposium on electrocatalysis (edited by M. W. Brieter), Electrochemical Society, Princeton, New Jersey (1974) p. 94.Google Scholar
  29. [29]
    A. Damjanovic, A. Day and J. O'M. Bokris,J. Electrochem. Soc. 113 (1966) 739.Google Scholar
  30. [30]
    W. E. O'Grady, M. Y. C. Woo, P. L. Haggans and E. Yeager, inProceedings of the Symposium on Electrode Materials and Processes for Energy Conversion and Storage (edited by J. D. E. McIntyre, S. Srinivasan and F. G. Will), Electrochemical Society, Princeton, New Jersey (1977) p. 172.Google Scholar
  31. [31]
    E. Yeager, W. E. O'Grady, M. Y. C. Woo and P. Haggans,J. Electrochem. Soc. 125 (1978) 348.Google Scholar
  32. [32]
    A. T. Hubbard, R. M. Ishikawa and J. Kate-Karu,J. Electroanal. Chem. 86 (1978) 271.Google Scholar
  33. [33]
    D. Shopov, A. Andreev and D. Petkov,J. Catal. 1 (1969) 123.Google Scholar
  34. [34]
    P. Stonehart and P. N. RossCatal. Rev. Sci. Eng. 12 (1975) 1.Google Scholar
  35. [35]
    W. Vogel, J. Lundquist, P. N. Ross and P. Stonehart,Electrochim Acta 20 (1975) 79–93.Google Scholar
  36. [36]
    P. N. Ross and P. Stonehart,J. Res. Inst. Catal. (Hokkaido)22 (1974) 22.Google Scholar
  37. [37]
    N. A. Urrison, G. V. Shtienburg and V. S. Bogotski,Electrokhimiya 11 (1975) 1298.Google Scholar
  38. [38]
    M. A. Barett and R. Parson,J. Electroanal. Chem. 42 (1975) App. 1.Google Scholar
  39. [39]
    B. E. Conway and S. Grottesfield,J. Chem. Soc. Faraday Trans. 1.69 (1973) 1090.Google Scholar
  40. [40]
    H. Angerstein-Kozlowska, B. E. Conway and W. B. A. Sharp,J. Electroanal. Chem. 43 (1973) 9.Google Scholar
  41. [41]
    B. V. Tilac, B. E. Conway and H. Angerstein-Kozlowska,J. Electroanal. Chem. 48 (1973) 1.Google Scholar
  42. [42]
    D. A. J. Rand and R. Woods,J. Electroanal. Chem. 31 (1971) 29.Google Scholar
  43. [43]
    R. Parsons and W. H. M. Visscher,J. Electroanal. Chem. 36 (1972) 329.Google Scholar
  44. [44]
    K. J. Vetter and J. W. Schultze,J. Electroanal. Chem. 34 (1971) 131, 141.Google Scholar
  45. [45]
    T. Biegler and R. Woods,J. Electroanal. Chem. 20 (1969) 73.Google Scholar
  46. [46]
    K. S. Kim, N. Wingorad and R. E. David,J. Am. Chem. Soc. 93 (1971) 6296.Google Scholar
  47. [47]
    K. S. Kim, A. F. Gossman and N. Wingorad,Anal. Chem. 46 (1974) 197.Google Scholar
  48. [48]
    A. K. N. Reddy, M. A. Genshaw and J. O'M. Bokris,J. Chem. Phys. 48 (1968) 671.Google Scholar
  49. [49]
    S. Gillman,Electrochim Acta 9 (1964) 1025.Google Scholar
  50. [50]
    R. Ducros and R. P. Merrill,Surf. Sci. 50 (1976) 227.Google Scholar
  51. [51]
    P. Le'gar'e, G. Maire, B. Carriere and J. P. Deville,Surf. Sci. 68 (1977) 348.Google Scholar
  52. [52]
    A. Damjanovic and V. Brusic,Electrochim Acta 11 (1967) 615.Google Scholar
  53. [53]
    A. J. Appleby,J. Electrochem. Soc. 117 (1970) 328.Google Scholar
  54. [54]
    A. Damjanovic, M. A. Genshaw and J. O'M. Bokris,J. Electrochem. Soc. 114 (1967) 466, 1107.Google Scholar
  55. [55]
    P. N. Ross Jr.,J. Electrochem. Soc. 126 (1979) 78.Google Scholar
  56. [56]
    A. J. Appleby and B. S. Baker,J. Electrochem. Soc. 125 (1978) 404.Google Scholar
  57. [57]
    H. Zeliger,J. Electrochem. Soc 114 (1967) 144.Google Scholar
  58. [58]
    J. Bett, J. Lundquist, E. Washington and P. Stonechart, Electrochim Acta.18 (1973) 343.Google Scholar
  59. [59]
    H. R. Kunz and G. A. Gruver,J. Electrochem. Soc 112 (1975) 1279.Google Scholar
  60. [60]
    W. M. Vogel and J. M. Baris,Electrochem Acta 22 (1977) 1259.Google Scholar
  61. [61]
    K. F. Blurton, P. Greenburg, G. H. Oswin and D. R. Rutt,J. Electrochem. Soc. 119 (1972) 559.Google Scholar
  62. [62]
    L. J. Bregoli,Electrochim. Acta 23 (1978) 489.Google Scholar
  63. [63]
    M. Peuckert, T. Yoneda, R. A. Dalla Betta and M. Boudart,J. Electrochem. Soc. 113 (5) (1986) 944–947.Google Scholar
  64. [64]
    P. N. Ross, Electric Power Research InstituteEPRI-EM 1553; EPRI, Palo Alto, CA. (1980).Google Scholar
  65. [65]
    V. M. Jalan and D. A. Landsman, U.S. Patent 4,186,110 (29 Jan. 1980); V. M. Jalan, D. A. Landsman and J. M. Lee, U.S. Patent 4,192, 907 (11 March 1980); V. M. Jalan, U.S. Patent 4,202,934 (13 May 1980).Google Scholar
  66. [66]
    D. A. Landsman and F. J. Luczak, U.S. Patent 4,136,944 (23 Feb. 1982) and 4,373,014 (18 Feb. 1983).Google Scholar
  67. [67]
    V. M.Jalan and E. J. Taylor,J. Electrochem. Soc. 130 (1983) 2299.Google Scholar
  68. [68]
    V. M. Jalan and E. J. Taylor,Proceedings of the Symposium on the Chemistry and Physics of Electrocatalysis, vol. 84 (12). The Electrochemical Society, (1984) pp. 547–57.Google Scholar
  69. [69]
    A. J. Appleby,Cat. Rev. 4 (2) (1970) 221.Google Scholar
  70. [70]
    J. T. Glass, G. L. Cahen and G. E. Stoner,J. Electrochem. Soc. 134 (1987) 58–65.Google Scholar
  71. [71]
    L. Pauling,Nature 203 (1964) 182.Google Scholar
  72. [72]
    J. P. Hoare, in ‘Advances in Electrochemistry and Electro-Chemical Engineering’ vol. 6. (edited by P. Delahay) Interscience, New York (1967) p. 201.Google Scholar
  73. [73]
    E. Yeager, D. Scherson and B. Simic-Glavasky, in ‘The Chemistry and Physics of Electrocatalysis’, (edited by J. D. E. McIntyre, M. J. Weaver and E. B. Yeager), The Electrochemical Society Softbound Proceedings Series, Pennington, N.J. (1984) p. 247.Google Scholar
  74. [74]
    E. Yeager, in “Electrode Materials and Processes for Energy Conversion and Storage” (edited by J. D. E. McIntyre, S. Srinvasan and F. G. Will), The Electro-Chemical Society Softbound Proceedings Series, Princeton N.J. (1977) p. 149.Google Scholar
  75. [75]
    J. L. Gland, B. A. Sertin and G. B. Fisher,Surf. Sci. 95 (1980) 587.Google Scholar
  76. [76]
    J. Giner, J. Parry, L. Sweette and R. Catabriga, prepared for the National Aeronautics and Space Administration, Contract No. NASW-1233 (June 1968).Google Scholar
  77. [77]
    P. N. Ross and A. J. Appleby,Personal Communication (1984).Google Scholar
  78. [78]
    M. T. Paffett, J. G. Beery and G. Shimshon,J. Electrochem. Soc. 135 (6) (June 1988) 1431.Google Scholar
  79. [79]
    K. A. Daube, S. Paffett, S. Gottesfield and C. T. Compbell,J. Vac. Sci. Technol. a, 4 (1986) 1617.Google Scholar
  80. [80]
    M. T. Paffett, K. A. Daube, S. Gottesfeld and C. T. Compbell,J. Electroanal. Chem. Interfacial Electrochem. 220 (1987) 269.Google Scholar
  81. [81]
    S. Gottesfeld, M. T. Paffett and A. J. Reodondo,Electroanal. Chem. Interfacial Electrochem 43 (1988) 9.Google Scholar

Copyright information

© Chapman and Hall Ltd 1990

Authors and Affiliations

  • S. Mukerjee
    • 1
  1. 1.Tata Energy Research InstituteNew DelhiIndia

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