Polarity, anisotropy of polarizability, and spatial structures of certain gem-dinitroalkanes

  • B. A. Arbuzov
  • A. P. Timosheva
  • S. F. Vul'fson
  • A. D. Nikolaeva
  • N. M. Lyapin
  • A. N. Vereshchagin
Physical Chemistry
Received:
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Conclusions

  1. 1.

    Dipole moments and polarizability anisotropies have been measured for a series of methyl- and halogen-substituted methanes.

     
  2. 2.

    The nitroradical polarizability is nonadditive under substitution.

     
  3. 3.

    A method has been proposed in which two independent angles of internal rotation are measured and the results compared with data on the Kerr effect and Raleigh light scattering.

     
  4. 4.

    The C(NO2)2 group has C2 symmetry in molecules of symmetrically substituted dinitromethanes. The C(NO2)2 of 1-chloro-1,1-dinitroethane shows this same symmetry.

     

Keywords

Methyl Methane Anisotropy Dipole Moment Light Scattering 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Copyright information

© Plenum Publishing Corporation 1977

Authors and Affiliations

  • B. A. Arbuzov
    • 1
    • 2
  • A. P. Timosheva
    • 1
    • 2
  • S. F. Vul'fson
    • 1
    • 2
  • A. D. Nikolaeva
    • 1
    • 2
  • N. M. Lyapin
    • 1
    • 2
  • A. N. Vereshchagin
    • 1
    • 2
  1. 1.A. E. Arbuzov Institute of Organic and Physical ChemistryKazan Branch of the Academy of Sciences of the USSRUSSR
  2. 2.S. M. Kirov Kazan Institute of Chemical TechnologyUSSR

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