Reaction of hydridohydroxodecacarbo-nyltriangulotriosmium with pyridine

  • V. A. Maksakov
  • E. D. Korniets
  • L. K. Kedrova
  • S. P. Gubin
Brief Communications
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Conclusions

The following occurs when HOs3(OH)(CO)10 is reacted with pyridine or deuteropyridine: replacement of both bridge ligands in the osmium cluster, cleavage of the C-H or C-D bond, and migration of the H or D atom into the metal ring.

Keywords

Migration Pyridine Osmium Metal Ring Bridge Ligand 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Literature cited

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Copyright information

© Plenum Publishing Corporation 1982

Authors and Affiliations

  • V. A. Maksakov
    • 1
  • E. D. Korniets
    • 1
  • L. K. Kedrova
    • 1
  • S. P. Gubin
    • 1
  1. 1.Institute of Chemistry and Chemical TechnologySiberian Branch of the Academy of Sciences of the USSRKrasnoyarsk

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