Contributions of localized MO's to the magnetic shielding constants of protons in YPX3 molecules

  • R. M. Aminova
  • M. B. Zuev
  • I. D. Morozova
Physical Chemistry
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Conclusions

  1. 1.

    Calculations of the magnetic shielding constants of the protons in the O=PMe3 and S=PMe3 molecules have been carried out.

     
  2. 2.

    The decisive contribution to the shielding of a proton is made by the C-H bond itself, and it is transferred fairly completely from one molecule to another.

     
  3. 3.

    Diagrams of the isoshielding lines of the P-O and P-C bonds have been calculated, and they can be used for the analysis of the chemical shifts caused by the influence of these bonds in systems with similar environments for the phosphorus atom.

     

Keywords

Phosphorus Chemical Shift Phosphorus Atom Similar Environment PMe3 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Copyright information

© Plenum Publishing Corporation 1986

Authors and Affiliations

  • R. M. Aminova
    • 1
    • 2
  • M. B. Zuev
    • 1
    • 2
  • I. D. Morozova
    • 1
    • 2
  1. 1.V. I. Ul'yanov-Lenin Kazan State UniversityUSSR
  2. 2.A. E. Arbuzov Institute of Organic and Physical ChemistryAcademy of Sciences of the USSR, Kazan BranchUSSR

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