Solvent-controlled regioselectivity in the ortho-palladation of benzylamines and intramolecular exchange in cyclopalladated ligands
Organic Chemistry
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Conclusions
Cyclometallation of 1-(3′,4′-dimethoxyphenyl)-2-methyl-3-(4′-nitrophenyl)-2-azapropane upon treatment with Pd(II) acetate occurs at the electron rich dimethoxy-substituted aromatic ring in CHCl3 solution, and at the electron poor nitrophenyl ring in AcOH solution.
Keywords
Acetate CHCl3 Aromatic Ring Nitrophenyl AcOH
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Literature cited
- 1.A. J. Deeming, and I. P. Rothwell, Pure Appl. Chem.,52, 649 (1980); J. Organomet. Chem.,205, 117 (1981).Google Scholar
- 2.Y. Tamaru, M. Kogatani, and Z.-i. Yoshida, Angew. Chem.,93, 1031 (1981).Google Scholar
- 3.V. V. Dunina, O. A. Zalevskaya, I. P. Smolyakova, and V. M. Potatov, Zh. Obshch. Khim.,54, 2290 (1984).Google Scholar
- 4.B. Galli, F. Gasparinni, L. Maresca, et al., J. Chem. Soc., Dalton Trans., 1483 (1983).Google Scholar
- 5.V. I. Sokolov, Pure Appl. Chem.,55, 1837 (1984).Google Scholar
- 6.I. K. Sakodynskaya, A. D. Ryabov, A. K. Yatsimirskii, and I. V. Berezin, Dokl. Akad. Nauk SSSR,284, 634 (1985).Google Scholar
- 7.A. D. Ryabov, I. K. Sakodinskaya, and A. K. Yatsimirskii (Yatsimirsky), J. Chem. Soc., Dalton Trans., 2553 (1985).Google Scholar
- 8.A. D. Ryabov, Zh. Obshch. Khim.,57, 249 (1987).Google Scholar
- 9.H. Onoue and I. Moritani, J. Organomet. Chem.,43, 431 (1972).Google Scholar
- 10.A. D. Ryabov, V. A. Polyakov, and A. K. Yatsimirskii (Yatsimirsky), J. Chem. Soc., Perkin Trans.,2, 1503 (1983).Google Scholar
- 11.G. R. Newkome, T. Kawato, D. K. Kohli, et al., J. Am. Chem. Soc.,103, 3423 (1981).Google Scholar
- 12.J. Selbin, K. Abboud, and S. F. Watkins, J. Organomet. Chem.,241, 259 (1983); J. Selbin and M. A. Gutierrez, J. Organomet. Chem.,246, 95 (1983).Google Scholar
- 13.A. D. Ryabov and A. K. Yatsimirskii (Yatsimirsky), Inorg. Chem.,23, 789 (1984).Google Scholar
- 14.A. D. Ryabov, Koord. Khim.,11, 1532 (1985).Google Scholar
- 15.T. A. Stephenson, S. M. Morehouse, and A. R. Powell, J. Chem. Soc., 3632 (1965).Google Scholar
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© Plenum Publishing Corporation 1988