Kinetic study of the oxidation of n-butyl ether by molecular oxygen in the liquid phase

  • V. Yu. Egorov
  • S. A. Krashakov
  • N. V. Zolotova
  • V. V. Kharitonov
Physical Chemistry
  • 24 Downloads

Conclusions

  1. 1.

    The oxidation kinetics of n-butyl ether was studied at 313–353 K, and the oxidizability parameter K, the chain-initiation rate v0i, and the rate constant of degenerate chain branching k3i were determined.

     
  2. 2.

    In the initial oxidation stages only 65% of the absorbed oxygen is converted to ROOH. The unbalance in the ROOH formation and O2 absorption is explained by degradation of the α-alkoxy-α-hydroperoxylalkyl radical formed as a result of intramolecular chain transfer by the α-alkoxyalkylperoxy radical.

     

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Literature cited

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Copyright information

© Plenum Publishing Corporation 1987

Authors and Affiliations

  • V. Yu. Egorov
    • 1
  • S. A. Krashakov
    • 1
  • N. V. Zolotova
    • 1
  • V. V. Kharitonov
    • 1
  1. 1.Institute of Chemical PhysicsAcademy of Sciences of the USSR, Chernogolovka BranchUSSR

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