Effect of the nature of the polymeric carrier on the catalytic activity of palladium-polyheteroarylene catalysts in hydrogenation reactions

  • A. A. Belyi
  • L. G. Chigladze
  • A. L. Rusanov
  • M. O. Shalikiani
  • R. S. Tabidze
  • S. G. Gagarin
  • E. S. Shpiro
  • G. V. Antoshin
  • Kh. M. Minachev
  • M. E. Vol'pin
Physical Chemistry

DOI: 10.1007/BF00961971

Cite this article as:
Belyi, A.A., Chigladze, L.G., Rusanov, A.L. et al. Russ Chem Bull (1987) 36: 1995. doi:10.1007/BF00961971

Conclusions

The activity of palladium-polyheteroarylene catalysts is a function of the electron affinity of the polymer carriers and is determined by the proportion of the Pdδ+ form, formed due to the partial transfer of the electron density from the palladium to the electronic system of the polymer to a significant degree.

Copyright information

© Plenum Publishing Corporation 1988

Authors and Affiliations

  • A. A. Belyi
    • 1
  • L. G. Chigladze
    • 1
  • A. L. Rusanov
    • 1
  • M. O. Shalikiani
    • 1
  • R. S. Tabidze
    • 1
  • S. G. Gagarin
    • 1
  • E. S. Shpiro
    • 1
  • G. V. Antoshin
    • 1
  • Kh. M. Minachev
    • 1
  • M. E. Vol'pin
    • 1
  1. 1.A. N. Nesmeyanov Institute of Organoelemental CompoundsAcademy of Sciences of the USSRMoscow

Personalised recommendations