Structure and catalytic activity of metal complexes on carriers 3. Rhodium complexes on modified polymers and their catalytic properties in the reduction of nitrobenzene by chemically bound hydrogen

  • V. F. Dovganyuk
  • V. Z. Sharf
  • V. K. Belyaeva
  • I. N. Marov
  • Zh. L. Dykh
  • L. I. Lafer
  • V. I. Yakerson
Physical Chemistry
Received:

Abstract

Heterogenized catalysts based on rhodium complexes attached to polymers modified by the groups 3(5)-methylpyrazole, imidazole and benzimidazole have been synthesized. The process of their formation has been investigated by IR, UV, and EPR spectroscopy. Results have been obtained for the catalytic activity of the complexes in the hydrogenation of nitrobenzene by hydrogen transfer from propan-2-ol and NaBH4.

Keywords

Hydrogen Polymer Spectroscopy Catalytic Activity Imidazole 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
This is a preview of subscription content, log in to check access.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    V. F. Dovganyuk, L. I. Lafer, V. I. Isaeva, et al., Izv. Akad. Nauk SSSR, Ser. Khim., 2660 (1987).Google Scholar
  2. 2.
    V. F. Dovganyuk, V. I. Isaeva, and V. Z. Sharf, Izv. Akad. Nauk SSSR, Ser. Khim., 1223 (1988).Google Scholar
  3. 3.
    V. Z. Sharf, V. D. Kopylova, L. P. Karapetyan, et al., Izv. Akad. Nauk SSSR, Ser. Khim., 2746 (1977).Google Scholar
  4. 4.
    B. N. Laskorin, N. G. Zhukova, O. N. Grishina, et al., Zh. Prikl. Khim.,55, No. 3, 555 (1982).Google Scholar
  5. 5.
    V. Z. Sharf, V. F. Dovganyuk, V. I. Isaeva, and B. I. Maksimov, Izv. Akad. Nauk SSSR, Ser. Khim., 534 (1989).Google Scholar
  6. 6.
    B. Wayland, A. Newman, J. Am. Chem. Soc.,101, No. 21, 6472 (1979).Google Scholar
  7. 7.
    B. James, F. Ng, and E. Ochiai, Can. J. Chem.,50, No. 4, 590 (1972).Google Scholar
  8. 8.
    D. T. Sviridov, R. K. Sviridova, and Yu. F. Smirnov, in: Optical Spectra of Transition Metal Ions in Crystals [in Russian], Nauka, Moscow (1976), p. 4.Google Scholar
  9. 9.
    A. Zeccina, L. Cerruti, S. Coluccia, and E. Borello, J. Chem. Soc., B, No. 12, 1363 (1967).Google Scholar
  10. 10.
    A. M. Bellocq, C. Perchard, A. Novak, and M. L. Jozien, J. Chem. Phys., 1334 (1965).Google Scholar
  11. 11.
    J. Reedjik, Rec. Trav. Chim. Pays-Bas.,90, 117 (1971).Google Scholar
  12. 12.
    L. J. Bellamy and A. J. Owen, Spectrochim. Acta,25A, 329 (1969).Google Scholar
  13. 13.
    J. Reedjik, Rec. Trav. Chim. Pays-Bas.,88, 1451 (1969).Google Scholar
  14. 14.
    J. A. Welleman, Macromol. Chem.,182, 785 (1981).Google Scholar
  15. 15.
    C. W. Reimann, A. Mighell, and F. A. Mauer, Acta Crystallogr.,23, 135 (1967).Google Scholar
  16. 16.
    A. A. Kashaev, É. A. Zel'bet, M. P. Demidov, et al. Koordinats. Khim.,4, 685 (1978).Google Scholar
  17. 17.
    D. Goldfarb and L. Kevan, J. Phys. Chem.,90, No. 22, 5787 (1986).Google Scholar
  18. 18.
    H. Caldarary, M. De Armond, K. Hanck, and V. Sahini, J. Am. Chem. Soc.,98, 4455 (1976).Google Scholar
  19. 19.
    V. E. Shubin, V. A. Shvets, and V. B. Kazanskii, Kinet. Katal.,19, 1270 (1978).Google Scholar

Copyright information

© Plenum Publishing Corporation 1990

Authors and Affiliations

  • V. F. Dovganyuk
    • 1
    • 2
  • V. Z. Sharf
    • 1
    • 2
  • V. K. Belyaeva
    • 1
    • 2
  • I. N. Marov
    • 1
    • 2
  • Zh. L. Dykh
    • 1
    • 2
  • L. I. Lafer
    • 1
    • 2
  • V. I. Yakerson
    • 1
    • 2
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRMoscow
  2. 2.V. I. Vernadskii Institute of Geochemistry and Analytical ChemistryAcademy of Sciences of the USSRMoscow

Personalised recommendations