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Spin trap study of the dissociation of the N-N bond in phenylhydrazones

  • Dzh. A. Kereselidze
  • R. G. Gasanov
  • M. A. Tsikoliya
  • Sh. A. Samsoniya
Brief Communications
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Abstract

The spin trap method was used to detect the free phenylaminyl radical formed as the result of homolytic cleavage of the N-N bond in the phenylhydrazone of ethyl pyruvate under conditions of the Fischer indole synthesis.

Keywords

Ethyl Pyruvate Indole Spin Trap Ethyl Pyruvate 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Literature cited

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    K. H. Pausaker and C. I. Schubert, J. Chem. Soc., 1384 (1949).Google Scholar
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    S. A. Mahgoub, A. M. Fahmy, M. M. Aly, and M. Z. A. Badr, Bull. Chem. Soc. Jpn.,59, 1605 (1986).Google Scholar
  3. 3.
    A. H. Kelly, D. H. McLeod, and J. Parrick, Can. J. Chem.,43, 296 (1965).Google Scholar

Copyright information

© Plenum Publishing Corporation 1992

Authors and Affiliations

  • Dzh. A. Kereselidze
    • 1
    • 2
  • R. G. Gasanov
    • 1
    • 2
  • M. A. Tsikoliya
    • 1
    • 2
  • Sh. A. Samsoniya
    • 1
    • 2
  1. 1.I. Dzhavakhishvili Tbilisi State UniversityUSSR
  2. 2.A. N. Nesmeyanov Institute of Organometallic CompoundsAcademy of Sciences of the USSRMoscow

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