Rotational isomerism of vinylmethyltelluride

  • V. V. Keiko
  • L. M. Sinegovskaya
  • N. K. Gusarova
  • A. A. Tatarinova
  • N. A. Kalinina
  • B. A. Trofimov
Physical Chemistry
Received:
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Conclusions

  1. 1.

    In the IR spectrum of solutions of vinylmethyltelluride in n-heptane the doublet form of the valence oscillation band of the double bond is due to rotational isomerism. By analyzing the temperature dependence of the doublet shape, the low-frequency component of the doublet was identified as the s-cis-rotamer.

     
  2. 2.

    The differences in the enthalpies (4.6 ±0.2 kJ/mole) and entropies (-11.1 ±0.3 e.u.) of the vinlymethyltelluride rotamers have been calculated and it has been shown that the p,Πconjugation in its molecule is weaker by a factor of 2 than in vinylmethylsulfide.

     

Keywords

Entropy Enthalpy Double Bond Rotational Isomerism Oscillation Band 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Literature cited

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Copyright information

© Plenum Publishing Corporation 1987

Authors and Affiliations

  • V. V. Keiko
    • 1
  • L. M. Sinegovskaya
    • 1
  • N. K. Gusarova
    • 1
  • A. A. Tatarinova
    • 1
  • N. A. Kalinina
    • 1
  • B. A. Trofimov
    • 1
  1. 1.Irkutsk Institute of Organic ChemistrySiberian Branch of the Academy of Sciences of the USSRUSSR

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