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1,3,5-Hexatrienes as die nophiles in their reactions with hexachlorocyclopentadiene

  • K. Ya. Burshtein
  • N. A. Anikin
  • L. A. Yanovskaya
  • M. G. Veliev
  • M. M. Guseinov
Brief Communications
  • 31 Downloads

Conclusions

  1. 1.

    1,3,5-Hexatrienes react with hexachlorocyclopentadiene as dienophiles.

     
  2. 2.

    The reactivity of conjugated hydrocarbons H(CH=CH)nH towards hexachlorocyclopentadiene and cyclopentadiene correlates with the relative positions of the higher occupied and the lower unoccupied MO.

     

Keywords

Hydrocarbon Relative Position Cyclopentadiene Hexachlorocyclopentadiene 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
    A. S. Onishchenko, The Diene Synthesis [in Russian], Izd. Akad. Nauk SSSR, Moscow (1963).Google Scholar
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    V. Sh. Fel'dblum, Syntheses and Uses of Unsaturated Cyclic Hydrocarbons [in Russian], Khimiya, Moscow (1982).Google Scholar
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    M. G. Veliev, M. M. Guseinov, L. A. Yanovskaya, S. A. Mamedov, and A. A. Bairamov, Izv. Akad. Nauk SSSR, Ser. Khim., 1358 (1980).Google Scholar
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    M. J. S. Dewar and M. D. Lo, J. Am. Chem. Soc.,97, 1265 (1975).Google Scholar
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    M. G. Veliev, M. M. Guseinov, É. Sh. Mamedov, and A. A. Bairamov, Izv. Akad. Nauk SSSR, Ser. Khim., 1358 (1980).Google Scholar
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    M. V. Bazilevskii, Molecular Orbitals and Reactivity in Organic Molecules [in Russian], Khimiya, Moscow (1969), p. 213.Google Scholar

Copyright information

© Plenum Publishing Corporation 1985

Authors and Affiliations

  • K. Ya. Burshtein
    • 1
  • N. A. Anikin
    • 1
  • L. A. Yanovskaya
    • 1
  • M. G. Veliev
    • 1
  • M. M. Guseinov
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRMoscow

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