Reaction of acyl isocyanates with β-keto esters

  • B. A. Arbuzov
  • N. N. Zobova
  • S. K. Yakupova
Organic Chemistry
  • 24 Downloads

Conclusions

Acyl isocyanates react withβ- keto esters to give both O- and C-addition products. The O-addition products subsequently rearrange to the thermodynamically more stable C-addition products.

Keywords

Ester Isocyanate Keto Ester Acyl Isocyanate 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
    B. A. Arbuzov, N. N. Zobova, and O. V. Sofronova, Izv. Akad. Nauk SSSR, Ser. Khim.,1977, 1910.Google Scholar
  2. 2.
    K. Claus, H.-J. Fredrich, and H. Jensen, Ann. Chem.,1974, 561.Google Scholar
  3. 3.
    A. I. Kol'tsov and G. M. Kheifets, Usp. Khim.,40, 1646 (1971).Google Scholar
  4. 4.
    L. J. Bellamy, Infrared Spectra of Complex Molecules, Wiley (1958).Google Scholar
  5. 5.
    J. Houben, Methods in Organic Chemistry [Russian translation], Vol. 3, 2nd edition, ONTI (1935), p. 442.Google Scholar
  6. 6.
    V. A. Kazanskii (editor), Organic Syntheses, Vol. 3 [Russian translation], IL (1952), p. 513.Google Scholar

Copyright information

© Plenum Publishing Corporation 1980

Authors and Affiliations

  • B. A. Arbuzov
    • 1
  • N. N. Zobova
    • 1
  • S. K. Yakupova
    • 1
  1. 1.V. I. Ul'yanov-Lenin Kazan State UniversityUSSR

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