Reaction of dulcitol with PCl3
Organic Chemistry
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Conclusions
The reaction of dulcitol with PCl3 in dry dioxane at 55–60°C results in the formation of dulcitol 1,2,4;3,5,6-bis-O-(phosphite) and dulcitol 1,6-bis-O-(dichlorophosphite)-2,3;4,5-bis-O-(chlorophosphite); the latter was identified in the form of one of its diastereomers dulcitol: 1,6-bis-O-[di(N-diethylamino)-thiophosphate]-2,3;4,5-bis-O-(N-diethylaminothiophosphate), the structure of which was determined by structural x-ray diffraction analysis.
Keywords
Diffraction Analysis Dioxane Phosphite PCl3 Thiophosphate
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Literature cited
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Copyright information
© Plenum Publishing Corporation 1983