Telomerization of vinyl chloride with iododifluoromethanesulfonyl fluoride
Organic Chemistry
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Conclusions
- 1.
The products of the radical telomerization of vinyl chloride with FSO2CF2I, i.e., the telomers FSO2CF2(CH2CHCl)nI with n=1–3, have been isolated.
- 2.
At 90°C ordinary telomerization is accompanied to a considerable extent by stepwise telomerization; however, at 60°C the contribution of the secondary reactions to the formation of the homologous telomers is insignificant.
- 3.
The partial chain-transfer constants to FSO2CF2I for FSO2CF2(CH2CHCl)n (n=1–3) radicals at 60°C have been determined.
Keywords
Chloride Fluoride Vinyl Vinyl Chloride Considerable Extent
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Literature cited
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© Plenum Publishing Corporation 1981